Tetrahedron Letters p. 1841 - 1842 (1994)
Update date:2022-08-16
Topics:
Wright, Stephen W.
A new methodology is described for the synthesis of enol esters of acylsilanes, from readily available vinyl esters. A solution of LDA is added to a mixture of an enol ester (preferably sterically congested, with only one α- carboxyl proton, eg 2-ethylhexanoate) and a chlorosilane at -78°C to afford the product.
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