145291-87-8Relevant academic research and scientific papers
Solid state aggregation of cyclic iodonium ylides
Li, Guobi,Rheingold, Arnold L.,Protasiewicz, John D.
, (2022/01/28)
Iodonium ylides (ArI=CR(R")) represent unusual hypervalent iodine(III) sources of carbene equivalents. While their reactivity is well-described, their detailed structural chemistry is somewhat limited due to their thermal instability. Cyclic iodonium ylides typically have greater thermal stability than acyclic ylides, but so far few such materials have been examined by single crystal X-ray diffraction methods. This report details the synthesis of two cyclic iodonium ylides and their association in the solid state by intermolecular I???O interactions.
Synthesis of Cyclic Iodonium Ylides - 3H-1λ3-Benziodiol-1-ylium Ylides via Transylidation of Iodonium Ylides to Iodides
Yang, Rui-Yang,Dai, Li-Xin,Chen, Cheng-Gang
, p. 1487 - 1488 (2007/10/02)
Cyclic iodonium ylides are synthesised via an unprecedented transylidation of iodonium ylide to aryl iodides; the structure of one cyclic iodonium ylide is determined by X-ray crystallography.
