145291-94-7

Basic information

• Product Name: 1-(2-iodophenyl)-3-phenylpropane-1,3-dione
• Synonyms: 1-(2-iodophenyl)-3-phenylpropane-1,3-dione
• CAS NO: 145291-94-7
• Molecular Weight: 350.156
• Mol File: 145291-94-7.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 1-(2-iodophenyl)-3-phenylpropane-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 1-(2-iodophenyl)-3-phenylpropane-1,3-dione(145291-94-7)
• EPA Substance Registry System: 1-(2-iodophenyl)-3-phenylpropane-1,3-dione(145291-94-7)

Safety Data

• Hazardous Substances Data: 145291-94-7(Hazardous Substances Data)

Upstream product

• 93-58-3 benzoic acid methyl ester 
• 2142-70-3 2-iodoacetophenone 
• 609-67-6 2-Iodobenzoyl chloride 
• 98-86-2 acetophenone 
• 88-67-5 2-Iodobenzoic acid 
• 98-88-4 benzoyl chloride 
• 108-98-5 thiophenol 

Downstream Products

• 4809-08-9 3-phenyl-isocoumarin 
• 1785-95-1 2-benzoyl-1,3-indanedione 
• 1020252-40-7 3-phenylindeno[1,2-c]pyrazol-4(2H)-one 
• 1548422-08-7 1-[3,5-bis(trifluoromethyl)phenyl]-3-[2-[[2-(3-oxo-3-phenylpropanoyl)phenyl]ethynyl]phenyl]urea 
• 145292-07-5 Toluene-4-sulfonate2-benzoyl-3-oxo-1-iodonia-indan; 
• 145292-08-6 2-Benzoyl-3-oxo-1-iodonia-indan; chloride 
• 145292-12-2 1-(2-Iodo-phenyl)-3-phenyl-2-(triphenyl-λ⁵-phosphanylidene)-propane-1,3-dione 
• 145292-09-7 Toluene-4-sulfonic acid 1-benzoyl-2-(2-iodo-phenyl)-2-oxo-ethyl ester 
• 145292-10-0 2-Chloro-1-(2-iodo-phenyl)-3-phenyl-propane-1,3-dione 
• 145291-87-8 2-benzoyl-3-oxo-2,3-dihydrobenzo[b]iodolyl ylide 
• 145292-01-9 C₂₁H₁₄I₂O₂ 

Relevant articles and documents

Metal-Free, DBU-Mediated, Microwave-Assisted Synthesis of Benzo[c]xanthones by Tandem Reactions of Alkynyl-1,3-diketones

A base-mediated, green, microwave-assisted efficient preparation of a diverse benzoxanthone library from variety of readily accessible γ-alkynyl 1,3-diketones is reported. The synthesis is based on tandem reactions involving intramolecular cyclization, propargyl-allenyl isomerization, and electrocyclization in one pot. Some of the benzoxanthones are also synthesized by the one-pot reaction of 1,3-diketone and alkynyl bromide under basic heating conditions. This transformation also results in the construction of one new C?C bond and one new C?O bond. (Figure presented.).

Palladium-Catalyzed Carbonylative Annulation Reactions Using Aryl Formate as a CO Source: Synthesis of 2-Substituted Indene-1,3(2H)-dione Derivatives

An efficient synthesis of 2-substituted indene-1,3(2H)-diones from stable and readily available 1-(2-halophenyl)-1,3-diones by employing phenyl formate as a CO source has been developed. The reaction occurred via palladium-catalyzed intramolecular carbonylative annulation using K3PO4 as a base and DMSO as a solvent at 95 °C. In this protocol, the reaction showed a broad substrate scope with good to excellent yields.

Synthesis of Cyclic Iodonium Ylides - 3H-1λ3-Benziodiol-1-ylium Ylides via Transylidation of Iodonium Ylides to Iodides

Cyclic iodonium ylides are synthesised via an unprecedented transylidation of iodonium ylide to aryl iodides; the structure of one cyclic iodonium ylide is determined by X-ray crystallography.