HIGHLY STEREOSELECTIVE COUPLINGS OF CARBOHYDRATE LACTONES WITH TERPENE KETONES PROMOTED BY SmI2

DOI: 10.1016/S0040-4039(00)60008-4

Source and publish data:

Tetrahedron Letters p. 6069 - 6072 (1992)

Update date:2022-07-31

Topics:

Authors:

Enholm, Eric J.

Jiang, Shujun

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Article abstract of DOI:10.1016/S0040-4039(00)60008-4

Lactone 3-deoxycarbohydrates were reacted with samarium diiodide (SmI2) in THF/HMPA and the terpene ketones, (-)-menthone or (+)-dihydrocarvone; a serial reductive deoxygenation and an attendant carbonyl addition reaction afforded C2 branched sugars with

Full text of DOI:10.1016/S0040-4039(00)60008-4

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