14539-76-5

Basic information

• Product Name: rac-neomenthyl-4-tolylsulfonate
• Synonyms: rac-neomenthyl-4-tolylsulfonate
• CAS NO: 14539-76-5
• Molecular Weight: 310.458
• Mol File: 14539-76-5.mol
• Article Data: 12

Chemical Properties

• CAS DataBase Reference: rac-neomenthyl-4-tolylsulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: rac-neomenthyl-4-tolylsulfonate(14539-76-5)
• EPA Substance Registry System: rac-neomenthyl-4-tolylsulfonate(14539-76-5)

Safety Data

• Hazardous Substances Data: 14539-76-5(Hazardous Substances Data)

Upstream product

• 2216-52-6 Neomenthol 
• 98-59-9 p-toluenesulfonyl chloride 
• 490-99-3 DL-neomenthol 
• 15356-60-2 (1S,2R,5S)-(+)-menthol 
• 89-78-1 menthol 
• 104-15-4 toluene-4-sulfonic acid 

Downstream Products

• 619-52-3 (1R)-menth-3-ene 
• 854823-95-3 4-chloro-p-menthane 
• 91138-81-7 8-chloro-p-menthane 
• 103532-45-2 Neomenthyl thioacetate 
• 1462351-55-8 (1S,2S,5R)-(+)-neomenthyl selenol 
• 910660-22-9 (+)-dineomenthyl diselenide 
• 53273-24-8 (1S,2S,5R)-(+)-neomenthyl thiol 
• 1355709-98-6 1-methyl-2-[((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)sulfanyl]-1H-imidazole 
• 1355709-99-7 2-[((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)sulfanyl]-1H-benzimidazole 
• 1355709-97-5 2-[((1S,2S,5R)-2-isopropyl-5-methylcyclohexyl)sulfanyl]-1H-imidazole 
• 1372878-76-6 2-{[(1S,2S,5R)-2-isopropyl-5-methylcyclohexyl]sulfonyl}-1H-benzimidazole 
• 1372878-72-2 1-methyl-2-{[(1S,2S,5R)-2-isopropyl-5-methylcyclohexyl]sulfonyl}-1H-imidazole 
• 1372878-68-6 2-{[(1S,2S,5R)-2-isopropyl-5-methylcyclohexyl]sulfonyl}-1H-imidazole 
• 891826-22-5 cyclopenta-1,3-dienyl-(1S,2S,5R)-4-methyl-1-(prop-2-yl)-cyclohexane 

Relevant articles and documents

Chirality transfer through sulfur or selenium to chiral propellers

The mechanism of chirality transfer from a chiral alkyl substituent to a trityl moiety through sulfur or selenium atoms is analysed and discussed on the basis of ECD measurements, DFT structure and ECD spectra calculations. It is shown that the presence o

Practical synthesis of optically pure menthylamines starting from racemic neomenthol

A reliable and scalable route to racemic and highly enantiomerically enriched menthylamines exploits the technical product rac-neomenthol as the starting material. The elaborated protocol is based on nucleophilic substitution of the hydroxy moiety by azide. Subsequent reduction and resolution with tartaric acid provides the desired optically enriched menthylamines.

Syntheses and reactions of new optically active terpene dialkyl diselenides

The reaction of sodium diselenide with optically active alkyl tosylates or chlorides is found to be a useful method for the synthesis of optically active dialkyl diselenides. Optically active monoterpene diselenides derived from menthane, carane, pinane,