1454287-81-0

Basic information

• Product Name: (2-(benzo[d]thiazol-2-yl)-5-methoxyphenyl)(phenyl)methanone
• Synonyms: (2-(benzo[d]thiazol-2-yl)-5-methoxyphenyl)(phenyl)methanone
• CAS NO: 1454287-81-0
• Molecular Weight: 345.422
• Mol File: 1454287-81-0.mol

Chemical Properties

• CAS DataBase Reference: (2-(benzo[d]thiazol-2-yl)-5-methoxyphenyl)(phenyl)methanone(CAS DataBase Reference)
• NIST Chemistry Reference: (2-(benzo[d]thiazol-2-yl)-5-methoxyphenyl)(phenyl)methanone(1454287-81-0)
• EPA Substance Registry System: (2-(benzo[d]thiazol-2-yl)-5-methoxyphenyl)(phenyl)methanone(1454287-81-0)

Safety Data

• Hazardous Substances Data: 1454287-81-0(Hazardous Substances Data)

Upstream product

• 6265-92-5 2-(4-methoxy-phenyl)-benzothiazole 
• 100-52-7 benzaldehyde 
• 100-51-6 benzyl alcohol 
• 536-74-3 phenylacetylene 
• 100-42-5 styrene 
• 611-73-4 Benzoylformic acid 

Relevant articles and documents

Ceric ammonium nitrate (CAN) promoted PdII-catalyzed substrate-directed o-benzoxylation and decarboxylative o-aroylation

Inexpensive ceric ammonium nitrate (CAN) is an efficient oxidant for the Pd-catalyzed substrate-directed o-benzoxylation and decarboxylative o-aroylation processes. In the presence of CAN, the reaction of directing arenes with carboxylic acids resulted in o-benzoxylated products, whereas a decarboxylative o-aroylation occurred by using innodataalpha-keto acids, which led to the formation of o-aroylation products.

Pd(ii)-catalysed o-aroylation of directing arenes using terminal aryl alkenes and alkynes

A substrate-directed Pd-catalysed o-aroylation strategy has been demonstrated using new aroyl surrogates viz. terminal aryl alkenes and alkynes in the presence of TBHP. By a subtle change in catalyst from Cu to Pd, a differential selectivity is observed.

Palladium-catalyzed direct ortho-acylation through an oxidative coupling of 2-arylbenzothiazoles with benzylic alcohols

An efficient protocol was developed for Pd-catalyzed direct C-H bond acylation by cross-dehydrogenative-coupling of arylbenzothiazoles and benzylic alcohols using tert-butyl hydroperoxide (TBHP) as the oxidant. The acylation reactions exhibit good reactiv

Palladium-catalyzed ortho-aroylation of 2-arylbenzothiazoles and 2-arylbenzoxazoles with aldehydes

An efficient protocol for the ortho-aroylation of 2-arylbenzothiazoles and 2-arylbenzoxazoles has been developed using aldehydes as the aroyl source. This Pd-catalyzed substrate-directed sp2-hybridized C-H bond functionalization occurs in the presence of the oxidant tert-butyl hydroperoxide. A variety of functional groups on the 2-arylbenzothiazoles, 2-arylbenzoxazoles, and aldehydes are tolerated under the reaction conditions. Regioselective aroylation at the less hindered ortho position was observed for meta-substituted 2-arylbenzothiazoles. An efficient protocol for the ortho-aroylation of 2-arylbenzothiazoles and 2-arylbenzoxazoles has been developed using aldehydes as the aroyl source. This Pd-catalyzed C-H bond functionalization occurs in the presence of tert-butyl hydroperoxide, and a variety of functional groups on the 2-arylbenzothiazoles, 2-arylbenzoxazoles, and aldehydes are tolerated under the reaction conditions. Copyright