14574-06-2Relevant academic research and scientific papers
Selective acetylation of aliphatic hydroxyl group in the presence of phenolic hydroxyl group using silica gel supported BF3 catalyst
Das, Biswanath,Venkataiah,Madhusudhan
, p. 249 - 252 (2007/10/03)
Selective acetylation of aliphatic hydroxyl group in the presence of phenolic hydroxyl group was achieved conveniently and efficiently by treatment with EtOAc in the presence of silica gel supported BF3 catalyst.
A new synthesis of the benzofuran adenosine antagonist XH-14
Hutchinson, Sally A.,Luetjens, Henning,Scammells, Peter J.
, p. 3081 - 3084 (2007/10/03)
5-(3-Hydroxypropyl)-7-methoxy-2-(3'-methoxy-4'-hydroxyphenyl)benzo[b]furan-3 -carbaldehyde (XH-14, 1) has been reported to be a potent A1 adenosine antagonist. We have developed an efficient synthesis of this compound that should prove valuable for further structure-activity studies. The synthesis incorporates optimised methodology for the selective protection of a hydroxyl group and the ortho-bromination of a phenol.
SELECTIVE DEACETYLATION OF AROMATIC ACETATES BY AMINOLYSIS
Mansson, Per
, p. 1845 - 1846 (2007/10/02)
Pyrrolidine was shown to deacetylate aromatic acetyl groups considerably faster than aliphatic groups.
