1459-22-9 Usage
General Description
1-(2-Bromobenzyl)piperidine is an organic chemical compound that belongs to the class of piperidine derivatives. It is a white solid with a molecular formula of C13H16BrN and a molecular weight of 261.17 g/mol. 1-(2-Bromobenzyl)piperidine is used in organic synthesis and pharmaceutical research as a building block for the synthesis of various pharmaceuticals and bioactive compounds. It is a versatile intermediate that can undergo different chemical reactions, such as nucleophilic substitution and palladium-catalyzed coupling, to form a wide range of derivatives with varied chemical, physical, and biological properties. Additionally, the bromine atom in the molecule makes it a useful starting material for further functionalization through substitution or coupling reactions.
Check Digit Verification of cas no
The CAS Registry Mumber 1459-22-9 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 1,4,5 and 9 respectively; the second part has 2 digits, 2 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 1459-22:
(6*1)+(5*4)+(4*5)+(3*9)+(2*2)+(1*2)=79
79 % 10 = 9
So 1459-22-9 is a valid CAS Registry Number.
InChI:InChI=1/C12H16BrN/c13-12-7-3-2-6-11(12)10-14-8-4-1-5-9-14/h2-3,6-7H,1,4-5,8-10H2
1459-22-9Relevant articles and documents
A Manganese Pre-Catalyst: Mild Reduction of Amides, Ketones, Aldehydes, and Esters
Kelly, Colin M.,McDonald, Robert,Sydora, Orson L.,Stradiotto, Mark,Turculet, Laura
, p. 15901 - 15904 (2017/12/13)
A new (N-phosphinoamidinate)manganese complex is shown to be a useful pre-catalyst for the hydrosilative reduction of carbonyl compounds, and in most cases at room temperature. The Mn-catalyzed reduction of tertiary amides to tertiary amines, with a useful scope, is demonstrated for the first time by use of this catalyst, and is competitive with the most effective transition-metal catalysts known for such transformations. Ketones, aldehydes, and esters were also successfully reduced under mild conditions by using this new Mn catalyst.
