1461-10-5

Basic information

• Product Name: (S)-3-(4-methylphenyl)-1-butanol
• Synonyms: (S)-3-(4-methylphenyl)-1-butanol
• CAS NO: 1461-10-5
• Molecular Weight: 164.247
• Mol File: 1461-10-5.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: (S)-3-(4-methylphenyl)-1-butanol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-(4-methylphenyl)-1-butanol(1461-10-5)
• EPA Substance Registry System: (S)-3-(4-methylphenyl)-1-butanol(1461-10-5)

Safety Data

• Hazardous Substances Data: 1461-10-5(Hazardous Substances Data)

Upstream product

• 1201-85-0 (S)-3-(4-methylphenyl)butanoic acid 
• 151765-65-0 (S)-3-(4-methylphenyl)butanal 
• 105987-29-9 Acetic acid (S)-3-p-tolyl-butyl ester 
• 29128-22-1 3-(4-methylphenyl)-3-buten-1-ol 
• 1448857-55-3 (S)-1-(1H-pyrrol-1-yl)-3-(p-tolyl)butan-1-one 
• 736140-69-5 (2E)-3-(4-methylphenyl)-1-pyrrol-1-yl-2-propen-1-one 
• 1504-75-2 3-(4-methylphenyl)acrylaldehyde 
• 1203466-59-4 (S)-3-[(benzo[1,3]dithiole-1,1,3,3-tetraoxide)-2-yl]-3-(4-methylphenyl)-1-propanol 
• 6909-30-4 (1S,2R,4R)-limonene-1,2-epoxide 
• 105987-27-7 Acetic acid (S)-3-((S)-1-hydroxy-4-methyl-cyclohex-3-enyl)-butyl ester 
• 106035-80-7 (1R,3S,6S)-3-Isopropenyl-6-methyl-7-oxa-bicyclo[4.1.0]heptan-3-ol 
• 73069-45-1 (-)-(S)-p-mentha-1,8-dien-4-ol 
• 1027180-86-4 (S)-4-tert-Butyl-2-((S)-2-p-tolyl-propyl)-4,5-dihydro-oxazole 
• 615580-24-0 (S)-2-(4-(benzyloxy)butan-2-yl)-5-methylbenzenamine 

Downstream Products

• 4179-26-4 (+)-(S)-4-p-Tolyl-pentansaeure-ethylester 
• 4179-29-7 (+)-(S)-2-Methyl-6-p-tolyl-heptan-2-ol 
• 93742-08-6 (+)-(S)-2-Methyl-6-p-tolyl-2-chlor-heptan 
• 19876-64-3 (S)-(+)-4-p-tolylpentan-1-ol 
• 4179-25-3 (4S)-(4-methylphenyl)pentanoic acid 
• 4179-28-6 (+)-(S)-1-Brom-4-p-tolyl-pentan 
• 222845-31-0 (S)-1-(4-iodobutan-2-yl)-4-methylbenzene 
• 1786-15-8 (S,E)-nuciferol 
• 532-65-0 (+)-(S)-ar-turmerone 
• 593288-67-6 (S)-(+)-1-D₁-3-(p-tolyl)butane 
• 3649-81-8 (S)-curcumene 
• 593288-68-7 (S)-3-(4-methylphenyl)butyl 4-methyl-1-benzenesulfonate 
• 4179-22-0 (1S)-1-(4-methylphenyl)-3-bromobutane 
• 151765-65-0 (S)-3-(4-methylphenyl)butanal 

Relevant articles and documents

Baker's yeast mediated enantioselective synthesis of the bisabolane sesquiterpenes curcumene, turmerone, dehydrocurcumene and nuciferal

Fermenting baker's yeast converts the allylic alcohol 6 into enantiomerically pure (S)-(+)-3-(p-tolyl)butan-1-ol 7 which is a useful chiral building block for the synthesis of bisabolane sesquiterpenes. The versatility of this approach is shown in the preparation of (S)-(+)-curcumene, (S)-(+)-turmerone, (S)-(+)-dehydrocurcumene and (E,S)-(+)-nuciferal.

Method for synthesizing alkyne through catalytic asymmetric cross coupling (by machine translation)

The invention belongs to the field of, asymmetric synthesis, and discloses a method for catalyzing asymmetric cross- coupling to synthesize: an alkyne, and the L method comprises, the following steps, of A: preparing B a cuprous, salt and C a: ligand; preparing a catalyst; adding a base; reacting the compound with the compound with the compound; and reacting the compound with the compound. Of these, one of them, X is selected from the group consisting of, R halogens. 1 Optionally substituted heteroarylsulfonylcyanamide groups selected from the, group consisting, of optionally substituted, phenyl groups In-flight vehicle, R6 Trialkyl silyl groups or alkyl radicals, R2 Cycloalkyl radicals optionally substituted with an, optionally substituted alkyl, (CH radical2 )n R4 Multi,layer chain, n＝0-10,R saw blade4 A group selected, from, the group consisting of phenyl, alkenyl, aralkynyls, noonyloxy,and, noonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulfonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylsulphonylphenyl disiloxy-radicals. R3 A ligand, selected from hydrogen or any of the functional groups, is selected from the group consisting of, hydrogen and any L other functional group. The method, R disclosed by the, A invention has the, advantages of good catalytic, R ’ effect, wide application range. and high catalytic efficiency, and the, method disclosed by the, invention has the. advantages of good catalytic effect, wide application range and high catalytic efficiency. (by machine translation)

Catalytic enantioselective β-alkylation of α,β-unsaturated aldehydes by combination of transition-metal- and aminocatalysis: Total synthesis of bisabolane sesquiterpenes

Branching out! The first co-catalytic enantioselective (up to 98:2 e.r.) β-alkylation of α,β-unsaturated aldehydes by combination of simple chiral amine and copper catalysts provides β-branched aldehydes in a one-pot protocol (see scheme). The methodology was applied to the short total syntheses of bisabolane sesquiterpenes (S)-(+)-curcumene, (E)-(S)-(+)-3- dehydrocurcumene and (S)-(+)-tumerone.