146967-87-5

Basic information

• Product Name: METHYL 9-FLUORENYLIDENEACETATE
• Synonyms: LABOTEST-BB LT00112245;METHYL 9-FLUORENYLIDENEACETATE;Methyl 9-fluorenylideneacetate,95%;Methyl 9-fluorenylideneacetate 95%
• CAS NO: 146967-87-5
• Molecular Formula: C₁₆H₁₂O₂
• Molecular Weight: 236.27
• Mol File: 146967-87-5.mol
• Article Data: 3

Chemical Properties

• Melting Point: 108-112 °C(lit.)
• Boiling Point: 390.1±11.0 °C(Predicted)
• Appearance: /
• Density: 1.273±0.06 g/cm3(Predicted)
• CAS DataBase Reference: METHYL 9-FLUORENYLIDENEACETATE(CAS DataBase Reference)
• NIST Chemistry Reference: METHYL 9-FLUORENYLIDENEACETATE(146967-87-5)
• EPA Substance Registry System: METHYL 9-FLUORENYLIDENEACETATE(146967-87-5)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 146967-87-5(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 4425-73-4 fluoren-9-ylidene-acetic acid 
• 189999-35-7 [1,1'-biphenyl]-2,2'-iodonium trifluoromethanesulfonate 
• 292638-85-8 acrylic acid methyl ester 
• 188990-08-1 methyl 3-(2-iodophenyl)acrylate 
• 88284-48-4 2-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 60510-40-9 dimethyl 2H-cyclopenteno<1,2,3-l,m>fluorene-1,2-dicarboxylate 

Downstream Products

• 486-25-9 9-fluorenone 

Relevant articles and documents

Modular Tandem Mizoroki-Heck/Reductive Heck Reactions to Construct Fluorenes from Cyclic Diaryliodoniums

Starting from cyclic diaryliodoniums and terminal alkenes, a diverse set of fluorenes is conveniently constructed. The reactions catalyzed by palladium undergo one conventional Mizoroki-Heck reaction and one reductive Heck reaction. The scope of alkenes is general, leading to 29 fluorenes which would expand the structural diversity of fluorene reservoir. (Figure presented.).

Esterification of amino acids and mono acids using triphosgene

Alkyl esters of several amino acids and acids were prepared using triphosgene [trichloromethyl carbonate, TPA (2)].