147022-22-8Relevant academic research and scientific papers
C60-catalyzed preparation of aryl and heteroaryl magnesium and zinc reagents using Mg/LiCl
Shen, Zhi-Liang,Knochel, Paul
, p. 2324 - 2328 (2015)
Addition of a catalytic amount of C60 fullerene (3 mol %) catalyzes the insertion of magnesium to polycyclic aromatic halides, allowing the preparation of the corresponding Grignard reagents in good yields. Furthermore, the use of a cocktail of metallic salts (Mg, ZnCl2, LiCl) in the presence of C60 fullerene (3 mol %) allows preparation of some functionalized polyaromatic zinc reagents. The resulting organomagnesium and organozinc reagents efficiently underwent reactions with electrophiles, such as an aldehyde, an acid chloride, an allylic bromide, or an aryl iodide.
Nickel-catalyzed 1,2-addition of arylboroxines to aromatic aldehydes
Arao, Takafumi,Kondo, Kazuhiro,Aoyama, Toyohiko
, p. 4115 - 4117 (2008/02/03)
Development of Ni-Et-Duphos-catalyzed 1,2-addition of arylboroxines to aromatic aldehydes is described. The dramatic effect of boron reagent and phosphine ligand is observed. This method with a phosphine ligand allows asymmetric arylation of aromatic aldehydes (up to 78% ee).
Use of cheaper metal than Rh, CHCl3-free Pd catalyst, in 1,2-addition of aromatic aldehydes with arylboronic acids
Suzuki, Kiyoto,Arao, Takafumi,Ishii, Satoru,Maeda, Yuka,Kondo, Kazuhiro,Aoyama, Toyohiko
, p. 5789 - 5792 (2007/10/03)
Pd(OAc)2-(±)-tol-BINAP-catalyzed arylation reaction of aromatic aldehydes with arylboronic acids in the absence of CHCl3 is described.
Research on antibacterial and antifungal agents. 16. Synthesis and antifungal activities of 1-[α-(1-naphthyl)benzyl]imidazole derivatives and related 2-naphthyl isomers
Artico,Stefancich,Silvestri,Massa,Apuzzo,Artico,Simonetti
, p. 693 - 699 (2007/10/02)
Some 1-arylmethylimidazoles bearing a naphthyl group at the α position of benzyl moiety have been synthesized and tested as antifungal agents against Candida albicans and Candida spp. Such derivatives resemble bifonazole and naftifine, two important antim
