147127-08-0

Basic information

• Product Name: N-(4-tolylsulfonyl)-1,2,3,4-tetrahydronaphthalene-1,2-imine
• CAS NO: 147127-08-0
• Molecular Weight: 299.393
• Mol File: 147127-08-0.mol
• Article Data: 34

Chemical Properties

• CAS DataBase Reference: N-(4-tolylsulfonyl)-1,2,3,4-tetrahydronaphthalene-1,2-imine(CAS DataBase Reference)
• NIST Chemistry Reference: N-(4-tolylsulfonyl)-1,2,3,4-tetrahydronaphthalene-1,2-imine(147127-08-0)
• EPA Substance Registry System: N-(4-tolylsulfonyl)-1,2,3,4-tetrahydronaphthalene-1,2-imine(147127-08-0)

Safety Data

• Hazardous Substances Data: 147127-08-0(Hazardous Substances Data)

Upstream product

• 447-53-0 1,2-Dihydronaphthalene 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 529-34-0 3,4-dihydronaphthalene-1(2H)-one 
• 529-33-9 1,2,3,4-Tetrahydro-1-naphthol 
• 70-55-3 toluene-4-sulfonamide 
• 98-59-9 p-toluenesulfonyl chloride 
• 40949-56-2 N-(p-toluenesulphonylimino)pyridinium ylide 
• 119-64-2 tetralin 
• 941-55-9 4-toluenesulfonyl azide 
• 1338062-05-7 4-methyl-N-[(2-propoxyphenyl)-λ³-iodanylidene]benzenesulfonamide 
• 127-65-1 chloroamine-T 
• 21849-40-1 dibromamine-T 
• 55962-05-5 4-methyl-N-[(E)-phenyl-λ³-iodanylidene]benzenesulfonamide 
• 41085-71-6 bromamine T 

Downstream Products

• 1036030-79-1 N-(2-(3,4-dimethoxyphenyl)-1,2,3,4-tetrahydronaphthalen-2-yl)-4-methylbenzenesulfonamide 
• 1036030-78-0 N-(1-(3,4-dimethoxyphenyl)-1,2,3,4-tetrahydronaphthalen-2-yl)-4-methylbenzenesulfonamide 

Relevant articles and documents

Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents

Recent research has highlighted the key role played by the electron affinity of the active metal-nitrene/imido oxidant as the driving force in nitrene additions to olefins to afford valuable aziridines. The present work showcases a library of Co(II) reage

Double Functionalization of Styrenes by Cu-Mediated Assisted Tandem Catalysis

The double functionalization of styrenes through Cu-mediated assisted tandem catalysis was developed. The reaction was initiated by Cu-catalyzed aziridination and the subsequent nucleophilic ring-opening, which was triggered by the addition of (NH4)2S2O8 as an oxidant of Cu-catalyst to form a variety of C–C and C–X bonds. The expansion to three contiguous catalytic cycles led to the synthesis of functionalized indolines by one-pot operation.

Aziridination of olefins with bromamine-T in presence of iodine as catalyst

A strategy for achieving synthesis of aziridine employing iodine catalysed aziridination of alkenes with bromamine-T as nitrene source has been described. Ethyl acetate has been found to be the most suitable solvent and the strategy has been extended to v