40949-56-2

Basic information

• Product Name: [(4-Methylphenyl)sulfonyl]pyridinioamine anion
• Synonyms: [(4-Methylphenyl)sulfonyl]pyridinioamine anion
• CAS NO: 40949-56-2
• Molecular Formula: C₁₂H₁₂N₂O₂S
• Molecular Weight: 248.30088
• Mol File: 40949-56-2.mol
• Article Data: 21

Chemical Properties

• Boiling Point: °Cat760mmHg
• Flash Point: °C
• Appearance: /
• Density: g/cm³
• CAS DataBase Reference: [(4-Methylphenyl)sulfonyl]pyridinioamine anion(CAS DataBase Reference)
• NIST Chemistry Reference: [(4-Methylphenyl)sulfonyl]pyridinioamine anion(40949-56-2)
• EPA Substance Registry System: [(4-Methylphenyl)sulfonyl]pyridinioamine anion(40949-56-2)

Safety Data

• Hazardous Substances Data: 40949-56-2(Hazardous Substances Data)

Usage

General Description

The chemical [(4-Methylphenyl)sulfonyl]pyridinioamine anion is a negatively charged molecule that contains a pyridine ring with a sulfonyl group attached to a 4-methylphenyl group. [(4-Methylphenyl)sulfonyl]pyridinioamine anion has potential application in the field of pharmaceuticals, as the sulfonyl group can be utilized in the synthesis of various bioactive molecules. Additionally, the pyridinioamine moiety may have utility in coordination chemistry or as a building block for the construction of complex organic compounds. Further research and exploration of the properties and reactivity of this chemical may uncover its potential for various applications in the field of chemical and pharmaceutical sciences.

InChI:InChI=1/C12H13N2O2S/c1-11-5-7-12(8-6-11)17(15,16)13-14-9-3-2-4-10-14/h2-10,13H,1H3/q+1

Upstream product

• 110-86-1 pyridine 
• 941-55-9 4-toluenesulfonyl azide 
• 55962-05-5 [N-(p-tolylsulfonyl)imino]phenyliodinane 
• 6295-87-0 N-aminopyridin-1-ium iodide 
• 1694-92-4 2-Nitrobenzenesulfonyl chloride 
• 98-59-9 p-toluenesulfonyl chloride 
• 39996-41-3 1-aminopyridinium mesitylenesulphonate 
• 55962-05-5 4-methyl-N-[(E)-phenyl-λ³-iodanylidene]benzenesulfonamide 
• 75732-31-9 N-(p-methylbenzenesulfonyl)-N,O-bis(trimethylsilyl)hydroxylamine 

Downstream Products

• 1274906-16-9 N-(6-(tert-butyldimethylsilyloxy)-1-(2-oxooxazolidin-3-yl)hex-2-enylidene)-4-methylbenzenesulfonamide 
• 1385096-46-7 C₁₃H₁₁F₃N₂O₂S 
• 1385096-44-5 C₁₃H₁₃F₃N₂O₂S 
• 56983-95-0 2-phenylpyrazolo[1,5-a]pyridine 
• 158038-67-6 methyl 4-{[(4-methylphenyl)sulfonyl]amino}benzoate 

Relevant articles and documents

Visible-Light-Induced Remote C(sp3)-H Pyridylation of Sulfonamides and Carboxamides

Visible-light-induced site-selective C(sp3)-H pyridylation of amides has been accomplished using N-amidopyridinium salts. The N-centered radicals generated by the single-electron reduction of N-amidopyridinium substrates undergo 1,5-hydrogen at

Micellar Catalysis: Visible-Light Mediated Imidazo[1,2-a]pyridine C—H Amination with N-Aminopyridinium Salt Accelerated by Surfactant in Water

A light-promoted metal-free protocol for the amination of imidazo[1,2-a]pyridines with N-aminopyridinium salt by the assistance of surfactants in water was reported, charactering mild and environmentally benign conditions, as well as great functional grou

Visible-Light-Enabled Ortho-Selective Aminopyridylation of Alkenes with N-Aminopyridinium Ylides

By utilizing an underexplored reactivity mode of N-aminopyridinium ylides, we developed the visible-light-induced ortho-selective aminopyridylation of alkenes via radical-mediated 1,3-dipolar cycloaddition. The photocatalyzed single-electron oxidation of N-aminopyridinium ylides generates the corresponding radical cations that enable previously inaccessible 1,3-cycloaddition with a broader range of alkene substrates. The resulting cycloaddition adducts rapidly undergo subsequent homolytic cleavage of the N-N bond, conferring a substantial thermodynamic driving force to yield various β-aminoethylpyridines. Remarkably, amino and pyridyl groups can be installed into both activated and unactivated alkenes with modular control of ortho-selectivity and 1,2-syn-diastereoselectivity under metal-free and mild conditions. Combined experimental and computational studies are conducted to clarify the detailed reaction mechanism and the origins of site selectivity and diastereoselectivity.