14791-94-7 Usage
General Description
[2-(methylsulfanyl)phenyl](diphenyl)phosphane is an organophosphorus compound with the chemical formula C19H17PS. It consists of a phenyl ring with a methylsulfanyl group attached to it, and a phosphane group with two diphenyl substituents. [2-(methylsulfanyl)phenyl](diphenyl)phosphane is used in the synthesis of various organic compounds, and it also has potential applications in the field of coordination chemistry as a ligand for transition metal complexes. Additionally, it has been studied for its potential biological and pharmacological activities. However, further research is needed to fully understand its properties and potential uses.
Check Digit Verification of cas no
The CAS Registry Mumber 14791-94-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,7,9 and 1 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 14791-94:
(7*1)+(6*4)+(5*7)+(4*9)+(3*1)+(2*9)+(1*4)=127
127 % 10 = 7
So 14791-94-7 is a valid CAS Registry Number.
14791-94-7Relevant articles and documents
Controlling Photoisomerization Reactivity Through Single Functional Group Substitutions in Ruthenium Phosphine Sulfoxide Complexes
Kosgei, Gilbert K.,Breen, Douglas J.,Lamb, Robert W.,Livshits, Maksim Y.,Crandall, Laura A.,Ziegler, Christopher J.,Webster, Charles Edwin,Rack, Jeffrey J.
, p. 9819 - 9822 (2018)
We report the crystallography, emission spectra, femtosecond pump-probe spectroscopy, and density functional theory computations for a series of ruthenium complexes that comprise a new class of chelating triphenylphosphine based ligands with an appended sulfoxide moiety. These ligands differ only in the presence of the para-substitutent (e.g., H, OCH3, CF3). The results show a dramatic range in photoisomerization reactivity that is ascribed to differences in the electron density of the phosphine ligand donated to the ruthenium and the nature of the excited state.
