14791-94-7 Usage
Uses
Used in Organic Synthesis:
[2-(methylsulfanyl)phenyl](diphenyl)phosphane is utilized as a reagent in the synthesis of a wide range of organic compounds. Its unique structure allows for versatile reactions and the formation of diverse molecular structures, making it a valuable tool in organic chemistry.
Used in Coordination Chemistry:
In the field of coordination chemistry, [2-(methylsulfanyl)phenyl](diphenyl)phosphane serves as a ligand for the formation of transition metal complexes. Its ability to bind with metal ions provides opportunities for the development of new catalysts and materials with unique properties.
Used in Biological and Pharmacological Research:
[2-(methylsulfanyl)phenyl](diphenyl)phosphane has been studied for its potential biological and pharmacological activities. Its specific interactions with biological systems may lead to the discovery of new therapeutic agents or contribute to a better understanding of biological processes.
Used in Chemical Research and Development:
This organophosphorus compound is also employed in research and development settings, where it can be used to explore new reaction pathways, develop novel synthetic methods, and create innovative materials with potential applications in various industries.
Used in Pharmaceutical Industry:
Within the pharmaceutical industry, [2-(methylsulfanyl)phenyl](diphenyl)phosphane may be used as a building block for the development of new drugs or as a component in the synthesis of complex pharmaceutical compounds. Its unique properties could contribute to the creation of more effective and targeted treatments for various diseases and conditions.
Used in Material Science:
In the field of material science, [2-(methylsulfanyl)phenyl](diphenyl)phosphane could be employed in the design and synthesis of new materials with specific properties, such as improved conductivity, enhanced stability, or unique optical characteristics. These materials could have applications in various industries, including electronics, energy, and aerospace.
Check Digit Verification of cas no
The CAS Registry Mumber 14791-94-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,7,9 and 1 respectively; the second part has 2 digits, 9 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 14791-94:
(7*1)+(6*4)+(5*7)+(4*9)+(3*1)+(2*9)+(1*4)=127
127 % 10 = 7
So 14791-94-7 is a valid CAS Registry Number.
14791-94-7Relevant academic research and scientific papers
Kosgei, Gilbert K.,Breen, Douglas J.,Lamb, Robert W.,Livshits, Maksim Y.,Crandall, Laura A.,Ziegler, Christopher J.,Webster, Charles Edwin,Rack, Jeffrey J.
, p. 9819 - 9822 (2018)
We report the crystallography, emission spectra, femtosecond pump-probe spectroscopy, and density functional theory computations for a series of ruthenium complexes that comprise a new class of chelating triphenylphosphine based ligands with an appended sulfoxide moiety. These ligands differ only in the presence of the para-substitutent (e.g., H, OCH3, CF3). The results show a dramatic range in photoisomerization reactivity that is ascribed to differences in the electron density of the phosphine ligand donated to the ruthenium and the nature of the excited state.
Versatile Visible-Light-Driven Synthesis of Asymmetrical Phosphines and Phosphonium Salts
Arockiam, Percia Beatrice,Lennert, Ulrich,Graf, Christina,Rothfelder, Robin,Scott, Daniel J.,Fischer, Tillmann G.,Zeitler, Kirsten,Wolf, Robert
supporting information, p. 16374 - 16382 (2020/11/03)
Asymmetrically substituted tertiary phosphines and quaternary phosphonium salts are used extensively in applications throughout industry and academia. Despite their significance, classical methods to synthesize such compounds often demand either harsh reaction conditions, prefunctionalization of starting materials, highly sensitive organometallic reagents, or expensive transition-metal catalysts. Mild, practical methods thus remain elusive, despite being of great current interest. Herein, we describe a visible-light-driven method to form these products from secondary and primary phosphines. Using an inexpensive organic photocatalyst and blue-light irradiation, arylphosphines can be both alkylated and arylated using commercially available organohalides. In addition, the same organocatalyst can be used to transform white phosphorus (P4) directly into symmetrical aryl phosphines and phosphonium salts in a single reaction step, which has previously only been possible using precious metal catalysis.
