147974-22-9Relevant academic research and scientific papers
Catalytic enantioselective synthesis of macrolides via asymmetric alkylation
Jones, Graham B.,Huber, Robert S.,Chapman, Brant J.
, p. 1797 - 1809 (2007/10/03)
Catalytic enantioselective syntheses of the macrolides (R)-(-) phoracantholide and (R)-(+) lasiodiplodin have been achieved. Stereochemistry was introduced in using an arene chromium tricarbonyl derived catalyst, which mediated the enantioselective additi
Catalytic asymmetric induction part 2. Chiral tricarbonyl (η6 arene) chromium (O) complexes as enantioselective catalysts
Jones,Heaton
, p. 261 - 272 (2007/10/02)
A chiral metallocyclic Lewis acid based catalyst system derived from norephedrine is reported. A key stereodirective element emanates from a tricarbonyl chromium (O) group complexed to the aryl ring. The catalysts mediate the addition of dialkyl zinc species to a variety of aldehydes with high enantioselectivity.
