148312-84-9

Upstream product

• 108713-90-2 2,3,4-tri-O-benzyl-D-xylose diethyl dithioacetal 
• 201603-52-3 tert-Butyl-dimethyl-((2R,3S,4R)-2,3,4-tris-benzyloxy-5,5-bis-ethylsulfanyl-pentyloxy)-silane 
• 201603-40-9 (2R,3S,4R)-5-(tert-Butyl-dimethyl-silanyloxy)-1,1-bis-ethylsulfanyl-pentane-2,3,4-triol 
• 100-39-0 benzyl bromide 
• 13263-74-6 D-xylose diethyl dithioacetal 
• 116384-32-8 2,3,4-tri-O-benzyl-D-xylo-pentodialdose 1,1-diethyl dithioacetal 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 148312-88-3 ((2S,5S,6R,7R,8S,8aS)-6,7,8-Tris-benzyloxy-2-hydroxy-3-oxo-octahydro-indolizin-5-yl)-acetic acid methyl ester 
• 148312-89-4 ((2S,5S,6R,7R,8S,8aS)-6,7,8-Tris-benzyloxy-2-hydroxy-octahydro-indolizin-5-yl)-acetic acid methyl ester 
• 148312-90-7 ((2S,5S,6R,7R,8S,8aS)-6,7,8-Tris-benzyloxy-2-hydroxy-octahydro-indolizin-5-yl)-acetic acid 
• 215303-15-4 (2E,7E)-(4R,5R,6S)-4,5,6-Tris-benzyloxy-9-hydroxy-nona-2,7-dienoic acid methyl ester 
• 215303-14-3 (2E,7E)-(4R,5R,6S)-4,5,6-Tris-benzyloxy-9-oxo-nona-2,7-dienoic acid methyl ester 
• 148312-85-0 (E)-(4R,5S,6R)-4,5,6-Tris-benzyloxy-7-oxo-hept-2-enoic acid methyl ester 

Relevant academic research and scientific papers

Free Radical Studies and Solutions to the Synthesis of (+)-Cyclophellitol

D-Xylose serves as a starting material for approaches to the synthesis of the glucosidase inhibitors, (+)-cyclophellitol (1) and (+)-epi-cyclophellitol (2). An investigation of the cyclization of diastereomeric oxiranyl radicals to achieve this goal was m

Cycloaddition reactions of carbohydrate derivatives. Part IV. Synthesis of a tetrahydroxyindolizidine through a cyclic nitrone prepared from D-xylose

Intramolecular conjugate addition of the oxime from aldehyde 5 led to the formation of cyclic nitrone 6. 1,3-Dipolar cycloaddition of the latter with methyl acrylate gave the bicyclic 7 with high diastereoselection. Subsequent four-step transformation of