148409-71-6

Upstream product

• 59005-41-3 (2R,3S)-4-Benzyloxy-3-methyl-butane-1,2-diol 
• 80109-44-0 (2S,3S,6S)-1-Benzyloxy-2-methyl-6-(R)-oxiranyl-heptan-3-ol 
• 80109-44-0 (2S,3R,6S)-1-Benzyloxy-2-methyl-6-(R)-oxiranyl-heptan-3-ol 
• 81380-07-6 (2S,3S,6S)-1-Benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-heptan-3-ol 
• 78433-56-4 (R)-2-((S)-2-Benzyloxy-1-methyl-ethyl)-oxirane 
• 58967-03-6 (S)-4-((S)-2-Iodo-1-methyl-ethyl)-2,2-dimethyl-[1,3]dioxolane 
• 57280-24-7 (R)-2-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-propan-1-ol 
• 100-39-0 benzyl bromide 
• 81380-07-6 (2S,3R,6S)-1-Benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-heptan-3-ol 
• 78433-56-4 (R)-2-((R)-2-Benzyloxy-1-methyl-ethyl)-oxirane 

Downstream Products

• 148338-52-7 2-{(E)-(R)-1-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-1-methyl-but-2-enyloxymethyl}-4,4-dimethyl-4,5-dihydro-oxazole 
• 148354-89-6 (E)-(1S,2R)-4-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-1-(4,4-dimethyl-4,5-dihydro-oxazol-2-yl)-2-methyl-pent-3-en-1-ol 
• 148338-53-8 (E)-(R)-4-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methyl-pent-3-en-1-ol 
• 148409-72-7 (E)-(S)-4-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methyl-pent-3-en-1-ol 
• 148338-54-9 (2S,3R,4R)-4-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-2-methyl-pentane-1,3-diol 
• 148338-51-6 (E)-(R)-2-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-pent-3-en-2-ol 
• 148409-74-9 (Z)-(R)-2-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-pent-3-en-2-ol 
• 148338-56-1 (2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-2-((E)-(S)-1,3-dimethyl-penta-1,4-dienyl)-3-methyl-tetrahydro-pyran 
• 148354-88-5 (R)-2-[(2S,3S,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-pent-3-yn-2-ol 

Relevant academic research and scientific papers

Synthetic studies of the ionophore antibiotic zincophorin. 2. Iterative sigmatropic construction of the C1-C11 subunit

Advanced intermediates 22 and 23, representing the C1-C11 subunit of the ionophore zincophorin, have been prepared by a scheme incorporating sequential glycolate Claisen and [2,3] Wittig rearrangements to establish the key structural

Studies toward polyether antibiotics: stereospecific synthesis of polysubstituted tetrhydropyrans

A stereospecific and general method for the preparartion of trans-tetrahydropyrans 1 and cis-tetrahydropyrans 2 from acyclic precursors are described.Compound 12, a possible intermediate for the synthesis of antibiotic X-14547A, has been synthesized.