78433-56-4

Upstream product

• 78433-55-3 (2S,3R)-threo-3-methylbutane-1,2,3-triol 4-benzyl ether 1-tosylate 
• 13398-41-9 (2S, 3S)-threo-β-methylmalic acid 
• 81380-11-2 Toluene-4-sulfonic acid (1S,2R)-3-benzyloxy-1-hydroxymethyl-2-methyl-propyl ester 
• 59005-41-3 (2R,3S)-4-Benzyloxy-3-methyl-butane-1,2-diol 
• 100-39-0 benzyl bromide 
• 57280-24-7 (R)-2-((S)-2,2-Dimethyl-[1,3]dioxolan-4-yl)-propan-1-ol 
• 69743-60-8 (2S,3R)-threo-3-methylbutane-1,2,4-triol 1,2-acetonide 
• 77333-42-7 (2S,3R)-threo-3-methylbutane-1,2,4-triol 
• 78433-53-1 (2S,3S)-dimethyl threo-3-methylmalate THP ether 
• 86562-33-6 (2S,3R)-threo-3-methylbutane-1,2,4-triol 2-THP ether 
• 642-92-2 D,L-threo-β-methylaspartic acid 
• 6061-13-8 (2S,3S)-3-methylaspartic acid 
• 78479-16-0 (2S,3R)-threo-3-methylbutane-1,2,4-triol 4-benzyl ether 
• 78479-15-9 (2S,3R)-threo-3-methylbutane-1,2,4-triol 1,2-acetonide 4-benzyl ether 

Downstream Products

• 72598-35-7 (-)-serricornin 
• 72485-37-1 (4R,6S,7S)-7-acetoxy-4,6-dimethyl-3-nonanone 
• 82335-98-6 serricornin acetate <(4S,6R,7R)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 83997-86-8 serricornin acetate <(4S,6S,7S)-4,6-dimethyl-7-acetoxy-3-nonanone> 
• 86562-34-7 (2R,3R)-threo-2-methylpentane-1,3-diol 1-benzyl ether 3-THP ether 
• 86535-17-3 (2R,3R)-threo-2-methylpentane-1,3-diol 1-tosylate 
• 86562-36-9 (2R,3R)-threo-2-methylpentane-1,3-diol 3-THP ether 1-tosylate 
• 81380-07-6 (2R,3S,6S)-1-Benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-heptan-3-ol 
• 81380-07-6 (2S,3R,6S)-1-Benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-heptan-3-ol 
• 81380-07-6 (2S,3S,6S)-1-Benzyloxy-6-((R)-2,2-dimethyl-[1,3]dioxolan-4-yl)-2-methyl-heptan-3-ol 
• 80109-44-0 (2S,3S,6S)-1-Benzyloxy-2-methyl-6-(R)-oxiranyl-heptan-3-ol 
• 81380-09-8 [(2R,3S,6S)-6-((S)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-methanol 
• 81380-09-8 [(2S,3R,6S)-6-((R)-2-Benzyloxy-1-methyl-ethyl)-3-methyl-tetrahydro-pyran-2-yl]-methanol 

Relevant academic research and scientific papers

Studies toward polyether antibiotics: stereospecific synthesis of polysubstituted tetrhydropyrans

A stereospecific and general method for the preparartion of trans-tetrahydropyrans 1 and cis-tetrahydropyrans 2 from acyclic precursors are described.Compound 12, a possible intermediate for the synthesis of antibiotic X-14547A, has been synthesized.

SYNTHESIS AND ABSOLUTE STEREOCHEMISTRY OF SERRICORNIN

The absolute stereochemistry of serricornin (4,6-dimethyl-7-hydroxy-3-nonanone) was established as 4S, 6S, 7S by synthesizing both (4S, 6S, 7S)-isomer and its antipode.Only the natural enantiomer was bioactive.by

DETERMINATION OF THE ABSOLUTE CONFIGURATION AT C-6 AND C-7 SERRICORNIN (4,6-DIMETHYL-7-HYDROXY-3-NONANONE), THE SEX PHEROMONE OF THE CIGARETTE BEETLE

The absolute configuration at C-6 and C-7 of serricornin was established as (6S, 7S) by synthesizing its (6R, 7S)-erythro and (6R, 7R)-threo isomers.