148599-35-3Relevant academic research and scientific papers
Phenylsulphonyloxiranes as Functional Acyl Anion Equivalents in Organic Synthesis
Ashwell, Mark,Clegg, William,Jackson, Richard F. W.
, p. 897 - 908 (2007/10/02)
Phenylsulphonyloxiranes can be lithiated with butyllithium α to the phenylsulphonyl group at low temperature.The anions formed are unstable, but sufficiently reactive to allow the isolation of adducts in good yield following treatment with a variety of el
PREPARATION AND RING-OPENING REACTIONS OF 2-PHENYLSULPHONYL-2-TRIMETHYLSILYL OXIRANES
Hewkin, Cheryl T.,Jackson, Richard F. W.
, p. 1877 - 1880 (2007/10/02)
Reaction of 2-phenylsulphonyl oxiranes (1) with butyllithium in the presence of chlorotrimethylsilane gave 2-phenylsulphonyl-2-trimethylsilyl oxiranes (2), which on treatment with MgBr2*Et2O gave 2-bromoacylsilanes (3) and either bromovinyl sulphones (5)
Phenylsulphonyl Oxirane: a Versatile Reagent for Organic Synthesis
Ashwell, Mark,Jackson, Richard F. W.
, p. 645 - 647 (2007/10/02)
Phenylsulphonyl oxirane (1) reacts as the synthetic equivalent of the acetaldehyde dipolar synthon (2).
