79389-15-4

Basic information

• Product Name: Benzene, [1-(2-propenyloxy)-2-propenyl]-
• CAS NO: 79389-15-4
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 79389-15-4.mol

Chemical Properties

• CAS DataBase Reference: Benzene, [1-(2-propenyloxy)-2-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [1-(2-propenyloxy)-2-propenyl]-(79389-15-4)
• EPA Substance Registry System: Benzene, [1-(2-propenyloxy)-2-propenyl]-(79389-15-4)

Safety Data

• Hazardous Substances Data: 79389-15-4(Hazardous Substances Data)

Upstream product

• 1826-67-1 vinyl magnesium bromide 
• 100-52-7 benzaldehyde 
• 106-95-6 allyl bromide 
• 5159-41-1 2-iodobenzyl alcohol 
• 26260-02-6 2-iodobenzaldehyde 
• 240808-00-8 1-(1-allyloxy-allyl)-2-iodo-benzene 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 148761-93-7 1-(2-iodophenyl)-2-propen-1-ol 

Downstream Products

• 126983-78-6 5-methylene-2-phenyltetrahydro-2H-pyran 
• 17113-33-6 2-phenylfuran 
• 124569-82-0 2,5-dihydro-2,5-diphenylfuran 
• 94540-81-5 2-(4-methoxyphenyl)-5-phenylfuran 
• 955-83-9 2,5-diphenylfuran 
• 1334240-37-7 methyl 2-methoxy-5-(5-phenylfuran-2-yl)benzoate 
• 1334240-36-6 2-phenyl-5-(3,4,5-trimethoxyphenyl)furan 
• 1334240-35-5 2-(4-methoxy-3-nitrophenyl)-5-phenylfuran 
• 1175163-90-2 1-((2Z)-5-{[(1-phenylprop-2-en-1-yl)oxy]methyl}hexa-2,5-dien-1-yl)-4-methoxybenzene 
• 1175163-95-7 1-((2Z)-5-{[(4,5-dimethyl-2-methylene-1-phenylhex-4-en-1-yl)oxy]methyl}hexa-2,5-dien-1-yl)-4-methoxybenzene 
• 53138-45-7 5-phenyl-2,5-dihydrofuran-2-one 
• 33732-62-6 2-phenyl-2,3-dihydrofuran 
• 124244-39-9 2-phenyl-2,5-dihydrofuran 

Relevant articles and documents

Chemo-Enzymatic Metathesis/Aromatization Cascades for the Synthesis of Furans: Disclosing the Aromatizing Activity of Laccase/TEMPO in Oxygen-Containing Heterocycles

The unprecedented Trametes versicolor laccase/TEMPO-catalyzed aromatization of 2,5-dihydrofurans to furans is described. A variety of furan derivatives have been synthesized in moderate to high conversions (21-99%) and yields (20-76%) under mild reaction

Synthesis of conjugated γ- and δ-lactones from aldehydes and ketones via a vinylation(allylation)-ring closing metathesis-oxidation sequence

Nucleophilic C-vinylation and C-allylation of aldehydes and ketones followed by O-allylation of the obtained carbinols gave the corresponding allyl or homoallyl ethers, respectively. Ring-closing metathesis of these compounds afforded in many cases cyclic ethers (dihydrofurans and dihydropyrans, respectively) bearing disubstituted and trisubstituted C=C bonds. These were then subjected to allylic oxidation to yield conjugated γ- and δ-lactones. Reasons for the observed failures are presented and discussed.

[2,3]-Wittig rearrangement initiated by 1,5-hydrogen atom transfer from an o-iodophenyl group on the α-carbon of allylic ethers by reduction with SmI2

Intramolecular 1,5-hydrogen atom transfer of an aryl radical generated by reduction of an o-iodophenyl group on the allylic position of allyl ethers by SmI2 regioselectively generates α-allyloxy carbanions, which undergo [2,3]-Wittig rearrangem

Synthesis of conjugated γ- and δ-lactones from aldehydes and ketones via a vinylation/allylation-ring closing metathesis-oxidation sequence

Nucleophilic C-vinylation or C-allylation of aldehydes and ketones followed by O-allylation of the obtained carbinols gave the corresponding allyl ethers. Ring-closing metathesis of the latter afforded cyclic ethers (dihydrofurans and dihydropyrans, respectively) which were then subjected to allylic oxidation to yield conjugated γ- and δ-lactones.