200055-89-6

Basic information

• Product Name: 2H-1-Benzopyran-2-one, 4-[[(4-methylphenyl)sulfonyl]oxy]-
• CAS NO: 200055-89-6
• Molecular Formula: C16H12O5S
• Molecular Weight: 316.334
• Mol File: 200055-89-6.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: 2H-1-Benzopyran-2-one, 4-[[(4-methylphenyl)sulfonyl]oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: 2H-1-Benzopyran-2-one, 4-[[(4-methylphenyl)sulfonyl]oxy]-(200055-89-6)
• EPA Substance Registry System: 2H-1-Benzopyran-2-one, 4-[[(4-methylphenyl)sulfonyl]oxy]-(200055-89-6)

Safety Data

• Hazardous Substances Data: 200055-89-6(Hazardous Substances Data)

Upstream product

• 1076-38-6 4-hydroxy[1]benzopyran-2-one 
• 98-59-9 p-toluenesulfonyl chloride 
• 884866-01-7 1-(4-methylbenzensulfonyl)-4-phenyl-1H-1,2,3-triazole 
• 1078739-25-9 1-(4-methylphenylsulfonyl)-4-(4-nitrophenyl)-1H-1,2,3-triazole 
• 5533-04-0 2-(methoxymethoxy)benzaldehyde 
• 939794-48-6 ethyl 3-(2-methoxymethoxy)phenylpropiolate 
• 693794-59-1 1-(2,2-dibromovinyl)-2-(methoxymethoxy)-benzene 
• 104-15-4 toluene-4-sulfonic acid 
• 160559-13-7 ethyl 3-(2-hydroxyphenyl)propiolate 

Downstream Products

• 170456-76-5 4-(4-methoxyphenyl)coumarin 
• 15185-05-4 4-phenylcoumarin 
• 852171-80-3 4-(4-tert-butylphenyl)-2H-benzopyran-2-one 
• 872452-06-7 4-(1-butoxyvinyl)-2H-chromen-2-one 
• 27129-32-4 4-phenylsulphenyl-2H-chromene-2-one 
• 120346-46-5 4-(4-fluorophenyl)-2H-benzopyran-2-on 
• 88369-09-9 4-benzylsulfanylcoumarin 
• 941-55-9 4-toluenesulfonyl azide 
• 35817-28-8 4-phenoxy-2H-1-benzopyran-2-one 
• 353259-48-0 4-(4-methylphenoxy)-2H-chromene-2-one 
• 923557-84-0 4-(4-nitrophenoxy)-2H-chromene-2-one 

Relevant articles and documents

Enantioselective allene/enone photocycloadditions: The use of an inexpensive optically active 1,3-disubstituted allene

We report the preparation and use of an inexpensive readily prepared optically active 1,3-disubstituted allene that may be utilized for enantioselective intramolecular allene/enone photocycloadditions. In addition, we describe novel substrates for intramo

Highly selective and sensitive coumarin–triazole-based fluorometric ‘turn-off’ sensor for detection of Pb2+ ions

Exposure to even very low concentrations of Pb2+ is known to cause cardiovascular, neurological, developmental, and reproductive disorders, and affects children in particular more severely. Consequently, much effort has been dedicated to the de

Transition metal- and oxidant-free sulfonylation of 1-sulfonyl-1H-1,2,3-triazoles to enols for the synthesis of sulfonate derivatives

A novel and convenient protocol for the synthesis of sulfonate derivatives via DABCO-catalyzed direct sulfonylation of 1-sulfonyl-1,2,3-triazoles to different enols has been established. This synthetic route could effectively avoid the use of transition m

Palladium-Catalyzed Synthesis of Benzothiophenes via Cross-Dehydrogenative Coupling of 4-Arylthiocoumarins and Pyrones

Benzothiophenes represent a pivotal class of sulfur heterocycles and their synthesis has attracted significant attention to generate bioactive scaffolds. Herein, we report a convergent, atom- and step-economic method for the synthesis benzothiophenes by cross-dehydrogenative coupling (CDC) of 4-arylthiocoumarins in good to excellent yields. We further demonstrate cross-dehydrogenative coupling of 4-arylthio-2-pyrones to afford alternative substitution of benzothiophenes. The presence of a labile ester carbonyl moiety provides functional handle for further functionalization by coumarin deconstruction. Most crucially, the manuscript demonstrates that the use of readily accessible templated synthesis has a significant potential for the rapid assembly of sulfur heterocycles by dehydrogenative coupling mechanism.