149652-25-5Relevant academic research and scientific papers
Vicarious nucleophilic substitution of hydrogen in aldehydes and Knoevenagel reaction of iminium salts with α-halocarbanions
Makosza,Kozhevnikov
, p. 2236 - 2238 (2007/10/03)
Iminium salts derived from aromatic aldehydes react with α-chlorocarbanions via two different pathways: reaction with secondary carbanion of halomethyl sulfones proceeds as the Knoevenagel condensation, while tertiary α-chlorocarbanions gave products of v
Synthesis of 1-aryl-1,3-diketones containing the dimethyl malonate moiety
Jimenez-Cruz,Maldonado,Cetina,Rios-Olivares
, p. 3439 - 3450 (2007/10/03)
The synthesis of new 1,3-diketones malonates 3 a-j were prepared in good yield from 1,5-diketones 2 a-j by employing the 1,5 → 1,3 diketone rearrangement.
A simple 1,5 → 1,3-diketone rearrangement
Jimenez-Cruz, Federico,Maldonado, Luis A.,Cetina, Raul
, p. 2685 - 2688 (2007/10/03)
1-Aryl-1,3-diketones 4-7 were prepared by reaction of the corresponding 1-aryl-1,5-diketones 2b with piperidinium acetate in refluxing C6H6.
