149669-80-7

Basic information

• Product Name: (Z)-1-[2-(triphenylstannyl)vinyl]-1-cyclopentanol
• Synonyms: (Z)-1-[2-(triphenylstannyl)vinyl]-1-cyclopentanol
• CAS NO: 149669-80-7
• Molecular Weight: 461.191
• Mol File: 149669-80-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-1-[2-(triphenylstannyl)vinyl]-1-cyclopentanol(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-1-[2-(triphenylstannyl)vinyl]-1-cyclopentanol(149669-80-7)
• EPA Substance Registry System: (Z)-1-[2-(triphenylstannyl)vinyl]-1-cyclopentanol(149669-80-7)

Safety Data

• Hazardous Substances Data: 149669-80-7(Hazardous Substances Data)

Upstream product

• 17356-19-3 1-ethynylcyclopentanol 
• 639-58-7 triphenyltin chloride 

Downstream Products

• 160327-08-2 (Z)-1-[2-(iododiphenylstannyl)vinyl]-1-cyclopentanol 
• 211819-35-1 (Z)-1-[2-(diiodophenylstannyl)vinyl]-1-cyclopentanol 
• 211819-28-2 (Z)-1-[2-(bromodiphenylstannyl)vinyl]-1-cyclopentanol 
• 211819-31-7 (Z)-1-[2-(dichlorophenylstannyl)vinyl]-1-cyclopentanol 
• 211819-26-0 (Z)-1-[2-(chlorodiphenylstannyl)vinyl]-1-cyclopentanol 

Relevant articles and documents

Synthesis, characterization and biological activity of (Z)-1-[2]-1-cyclopentanol and their arylhalostannyl derivatives

The synthesis and characterization by elemental analysis, IR and 1H NMR of (Z)-1 - 1-cyclopentanol,CH2(CH2)3C(OH)CHCHSnPh 3 (1) and (Z)-1 - 1-cyclopentanol, CH2(CH2)3C(OH)CHCHSn(p-toly)3 (2) are described, together with their halodemetallation by I2, Br2 and ICl to yield derivatives of the types CH2(CH2)3C(OH)CHCHSnAr3-nX n (Ar = phenyl or p-tolyl ; n = 1, 2 ; X = I, Br, Cl). The solid-state structures of two compounds have been determined by X-ray diffraction analysis. In the crystal of CH2(CH2)3C(OH)CHCHSnph3 (1) the Sn atom has a distorted tetrahedral geometry but intramolecular contact with the hydroxyl O atom has not been found. A trigonal bipyramidal geometry is found in CH2(CH2)3CC(OH)CHCH SnphBr2(11), in which OSn - interaction is noted [2.446(8) A] The biological activity of the title complexes is also investigated.