160327-08-2Relevant articles and documents
Synthesis, characterization and biological activity of (Z)-1-[2]-1-cyclopentanol and their arylhalostannyl derivatives
Dai, Hui Cong,Ying, Qihua,Wang, Xiao Hong,Yue, Su Mei,Pan, Hua De,Chen, Xi
, p. 2503 - 2509 (2008/10/09)
The synthesis and characterization by elemental analysis, IR and 1H NMR of (Z)-1 - 1-cyclopentanol,CH2(CH2)3C(OH)CHCHSnPh 3 (1) and (Z)-1 - 1-cyclopentanol, CH2(CH2)3C(OH)CHCHSn(p-toly)3 (2) are described, together with their halodemetallation by I2, Br2 and ICl to yield derivatives of the types CH2(CH2)3C(OH)CHCHSnAr3-nX n (Ar = phenyl or p-tolyl ; n = 1, 2 ; X = I, Br, Cl). The solid-state structures of two compounds have been determined by X-ray diffraction analysis. In the crystal of CH2(CH2)3C(OH)CHCHSnph3 (1) the Sn atom has a distorted tetrahedral geometry but intramolecular contact with the hydroxyl O atom has not been found. A trigonal bipyramidal geometry is found in CH2(CH2)3CC(OH)CHCH SnphBr2(11), in which OSn - interaction is noted [2.446(8) A] The biological activity of the title complexes is also investigated.