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CHROMIUM(II) ACETATE MONOHYDRATE DIMER, with the chemical formula Cr2(CH3COO)4(H2O)2, is a dimeric form of chromium(II) acetate that includes two water molecules. This dark green crystalline solid is soluble in water and some organic solvents, making it a versatile compound for various applications in the chemical industry.

14976-80-8

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14976-80-8 Usage

Uses

Used in Organic Synthesis:
CHROMIUM(II) ACETATE MONOHYDRATE DIMER is used as a catalyst in organic synthesis for its ability to facilitate various chemical reactions, enhancing the efficiency and selectivity of the processes.
Used in Preparation of Chromium Compounds:
In the chemical industry, CHROMIUM(II) ACETATE MONOHYDRATE DIMER serves as a reagent for the preparation of other chromium compounds, contributing to the production of a range of materials with different properties and applications.
Used in Magnetic Materials Industry:
CHROMIUM(II) ACETATE MONOHYDRATE DIMER has potential uses in the field of magnetic materials, where its unique properties can be leveraged to develop new materials with specific magnetic characteristics.
Used as a Source of Chromium Ions:
In chemical synthesis, CHROMIUM(II) ACETATE MONOHYDRATE DIMER is used as a source of chromium ions, which are essential for the synthesis of various chromium-containing compounds.
It is crucial to handle CHROMIUM(II) ACETATE MONOHYDRATE DIMER with care due to its toxic nature, ensuring that proper safety measures are in place to prevent ingestion or inhalation.

Check Digit Verification of cas no

The CAS Registry Mumber 14976-80-8 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,9,7 and 6 respectively; the second part has 2 digits, 8 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 14976-80:
(7*1)+(6*4)+(5*9)+(4*7)+(3*6)+(2*8)+(1*0)=138
138 % 10 = 8
So 14976-80-8 is a valid CAS Registry Number.
InChI:InChI=1/C2H4O2.Cr.H2O/c1-2(3)4;;/h1H3,(H,3,4);;1H2

14976-80-8SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 17, 2017

Revision Date: Aug 17, 2017

1.Identification

1.1 GHS Product identifier

Product name chromium(II) acetate hydrate

1.2 Other means of identification

Product number -
Other names CHROMIUM(II) ACETATE, DIMER MONOHYDRATE

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:14976-80-8 SDS

14976-80-8Relevant academic research and scientific papers

A modular synthesis approach to multinuclear heterometallic oxo clusters in polyoxometalates

Minato, Takuo,Suzuki, Kosuke,Ohata, Yusuke,Yamaguchi, Kazuya,Mizuno, Noritaka

supporting information, p. 7533 - 7536 (2017/07/12)

We report a modular synthesis approach to multinuclear heterometallic oxo clusters in lacunary polyoxometalates (POMs). This approach allowed the synthesis of a POM containing a nonanuclear {CrMn4}Lu2Ag2 cluster with the widest variety of metals among the discrete metal oxo clusters prepared to date.

Magnetic and Spectroscopic Properties of Some Heterotrinuclear Basic Acetates of Chromium(III), Iron(III), and Divalent Metal Ions

Blake, Antony B.,Yavari, Ahmad,Hatfield, William E.,Sethulekshmi, C. N.

, p. 2509 - 2520 (2007/10/02)

Reaction of Fe3+, M2+, and acetate ions in aqueous solution gives *3H2O (M=Mg, Mn, Co, Ni, or Zn), which on crystallisation from pyridine (py) is converted into .Reaction of chromium(II) acetate with metal(II) acetate in pyridine in the presence of air gives (M=Mg, Co, or Ni), and with in pyridine in the absence of air gives (M=Mn or Fe) and .The compounds with co-ordinated pyridine have been examined crystallographically and magnetically.The Cr2Mg, Cr2Ni, Fe2Ni, and CrFeNi compounds crystallise in the monoclinic system, space group Cc or C2/c, Z=4, but the other seven compounds are rhombohedral and isomorphous with *py (M=Mn or Fe), indicating that the three metal atoms are crystallographically equivalent as a result of disorder in the molecular orientation.Powder magnetic susceptibilities for the Cr2Co and Cr2Ni compounds (4.2-60 K), for the Fe2Mn and Fe2Ni compounds (4.2-295 K), and for the Fe2Ni(aquo) and Fe2Mg compounds (80-295 K) have been fitted by use of an exchange Hamiltonian to yield values of the exchange parameters J for the Cr-Cr, Fe-Fe, Cr-Ni, Fe-Ni, and Fe-Mn interactions, which are discussed in terms of superexchange mechanisms.The values of JFeFe in the Fe2Mg, Fe2Mn, and Fe2Ni compounds and of JCrCr in the Cr2Co and Cr2Ni compounds are approximately twice their values in the cations + (M=Cr or Fe), indicating that the μ3-O atom provides the main superexchange pathway.Diffuse-reflectance and solution spectra (6000-40000 cm-1) of the compounds have been recorded at room temperature and are discussed in terms of the ligand-field model; a band in the spectra of the Fe(III)2Fe(II) and Cr(III)Fe(III)Fe(II) compounds at ca. 7000 cm-1 is assigned to intervalence transfer.The room-temperature spectra of Cl (M3=Cr(III)3, Cr(III)2Fe(III), Cr(III)Fe(III)2, or Fe(III)3; L=H2O or py) have also been obtained, and intense absorption bands at ca. 19000 and 26000 cm-1 are tentatively assigned to simultaneous (Cr3+, Fe3+) double excitations.

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