14983-92-7

Basic information

• Product Name: (2-Methylphenyl)carbamic acid methyl ester
• Synonyms: (2-Methylphenyl)carbamic acid methyl ester;N-(2-Methylphenyl)carbamic acid methyl ester;METHYL N-(O-TOLYL)CARBAMATE
• CAS NO: 14983-92-7
• Molecular Formula: C₉H₁₁NO₂
• Molecular Weight: 165.19
• Mol File: 14983-92-7.mol
• Article Data: 30

Chemical Properties

• Melting Point: 52-53 °C(Solv: dichloromethane (75-09-2); hexane (110-54-3))
• Boiling Point: 202.5±19.0 °C(Predicted)
• Appearance: /
• Density: 1.138±0.06 g/cm3(Predicted)
• PKA: 13.87±0.70(Predicted)
• CAS DataBase Reference: (2-Methylphenyl)carbamic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (2-Methylphenyl)carbamic acid methyl ester(14983-92-7)
• EPA Substance Registry System: (2-Methylphenyl)carbamic acid methyl ester(14983-92-7)

Safety Data

• Hazardous Substances Data: 14983-92-7(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Journal of the American Chemical Society, 113, p. 1054, 1991 DOI: 10.1021/ja00003a056

Upstream product

• 67-56-1 methanol 
• 201230-82-2 carbon monoxide 
• 95-53-4 o-toluidine 
• 6294-89-9 hydrazinecarboxylic acid methyl ester 
• 88-72-2 1-methyl-2-nitrobenzene 
• 79-22-1 methyl chloroformate 
• 616-38-6 carbonic acid dimethyl ester 
• 124-38-9 carbon dioxide 
• 527-85-5 o-Methylbenzamid 
• 614-68-6 2-tolyl isocyanate 
• 73708-95-9 methyl 3-oxo-2-oximinobutanoate 
• 2597-44-6 formyl radical 
• 31656-92-5 1-azido-2-methyl-benzene 
• 584-90-7 2,2'-dimethylazobenzene 

Downstream Products

• 95-69-2 4-chloro-2-methylbenzeneamine 
• 10541-29-4 2-methyl-N-methylaniline hydrochloride 
• 117550-42-2 methyl N-[2-(chloromethyl)phenyl]carbamate 
• 151830-30-7 methyl N-ethyl-N-(o-methylphenyl)-carbamate 
• 57735-51-0 Benzyloxycarbonyl-L-alanin-N-methyl-2-methylanilid 
• 63379-17-9 2-methylcarbamoyl-4-nitro-toluene 
• 924666-87-5 (2-methyl-5-nitroso-phenyl)-carbamic acid methyl ester 
• 611-21-2 N,2-dimethylaniline 
• 39074-42-5 Chloromethyl-o-tolyl-carbamic acid methyl ester 

Relevant articles and documents

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Oxidative Route to Indoles via Intramolecular Amino-Hydroxylation of o-Allenyl Anilines

A new intramolecular oxidative amino-hydroxylation of o-allenyl anilines is reported. Treatment of carbamate-protected anilines with lead(IV) carboxylates in dichloromethane at room temperature results in facile tandem C-N (allene cyclization) and C-O bon

Copper-Catalyzed Coupling of Amines with Carbazates: An Approach to Carbamates

A new approach for the preparation of carbamatesviathe copper-catalyzed cross-coupling reaction of amines with alkoxycarbonyl radicals generated from carbazates is described. This environmentally friendly protocol takes place under mild conditions and is compatible with a wide range of amines, including aromatic/aliphatic and primary/secondary substrates.

Preparation method of pyridine quinazoline intermediate (by machine translation)

The invention discloses a preparation method of a pyridine quinazoline intermediate, wherein: the 2 - preparation method of the, pyridine quinazoline intermediate comprises, the following steps, of: performing, substitution reaction and 3 - ring-forming r