14996-70-4Relevant articles and documents
CuCl-catalyzed Oxidative Coupling Reaction of Secondary Amines with Molecular Oxygen in Pyridine
Kajimoto, Tsunesuke,Takahashi, Hidetaka,Tsuji, Jiro
, p. 3673 - 3674 (1982)
Oxidation of diphenylamine with molecular oxygen in the presence of CuCl in pyridine at room temperature to give tetraphenylhydrazine in a high yield was achieved by selecting suitable reaction conditions.N-methylaniline was also oxidized to give N,N'-dim
Method for realizing N-N coupling of secondary arylamine by utilizing electrochemical reaction
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Paragraph 0044-0046; 0053-0068, (2021/04/14)
The invention relates to the technical field of organic synthesis, and discloses a method for realizing the N-N coupling of secondary arylamine by utilizing electrochemical reaction, i.e., in a deviceprovided with an anode and a cathode, an Nmethylaniline
Chemoselective deprotonative lithiation of azobenzenes: Reactions and mechanisms
Nguyen, Thi Thanh Thuy,Boussonniere, Anne,Banaszak, Estelle,Castanet, Anne-Sophie,Nguyen, Kim Phi Phung,Mortier, Jacques
, p. 2775 - 2780 (2014/04/17)
Whereas standard strong bases (n-BuLi, s-BuLi/TMEDA, n-BuLi/t-BuOK, TMPMgCl·LiCl, and LDA) reduce the N=N bond of the parent azobenzene (Y = H), aromatic H→Li permutation occurs with LTMP when a suitable director of lithiation (Y = OMe, CONEt2, F) is present in the benzene residue of the azo compound. The method allows direct access to new substituted azobenzenes.