1501945-23-8

Basic information

• Product Name: cis-[1,1'-bis(diphenylphosphino)ferrocene](2-methylphenyl)nickel(II) chloride
• Synonyms: cis-[1,1'-bis(diphenylphosphino)ferrocene](2-methylphenyl)nickel(II) chloride
• CAS NO: 1501945-23-8
• Molecular Weight: 739.666
• Mol File: 1501945-23-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: cis-[1,1'-bis(diphenylphosphino)ferrocene](2-methylphenyl)nickel(II) chloride(CAS DataBase Reference)
• NIST Chemistry Reference: cis-[1,1'-bis(diphenylphosphino)ferrocene](2-methylphenyl)nickel(II) chloride(1501945-23-8)
• EPA Substance Registry System: cis-[1,1'-bis(diphenylphosphino)ferrocene](2-methylphenyl)nickel(II) chloride(1501945-23-8)

Safety Data

• Hazardous Substances Data: 1501945-23-8(Hazardous Substances Data)

Upstream product

• 67292-34-6 [1,1'-bis(diphenylphosphino)ferrocene]nickel(II) chloride 
• 33872-80-9 o-tolyl magnesium chloride 
• 12150-46-8 1,1'-bis-(diphenylphosphino)ferrocene 
• 14264-16-5 bis(triphenylphosphine)nickel(II) chloride 

Relevant articles and documents

NICKEL PRE-CATALYSTS AND RELATED COMPOSITIONS AND METHODS

Described herein are nickel pre-catalysts and related compositions and methods. The nickel pre-catalysts may be activated to form catalysts which may be utilized in organic reactions.

Development of an air-stable nickel precatalyst for the amination of aryl chlorides, sulfamates, mesylates, and triflates

A new air-stable nickel precatalyst for C-N cross-coupling is reported. The developed catalyst system displays a greatly improved substrate scope for C-N bond formation to include both a wide range of aryl and heteroaryl electrophiles and aryl, heteroaryl, and alkylamines. The catalyst system is also compatible with a weak base, allowing the amination of substrates containing base-sensitive functional groups.