15027-03-9

Basic information

• Product Name: methyl N-[(benzyloxy)carbonyl]glycylglycylphenylalaninate
• CAS NO: 15027-03-9
• Molecular Formula: C₂₂H₂₅N₃O₆
• Molecular Weight: 427.4504
• Mol File: 15027-03-9.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 716.7°C at 760 mmHg
• Flash Point: 387.3°C
• Density: 1.246g/cm³
• Vapor Pressure: 2.15E-20mmHg at 25°C
• Refractive Index: 1.564
• CAS DataBase Reference: methyl N-[(benzyloxy)carbonyl]glycylglycylphenylalaninate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl N-[(benzyloxy)carbonyl]glycylglycylphenylalaninate(15027-03-9)
• EPA Substance Registry System: methyl N-[(benzyloxy)carbonyl]glycylglycylphenylalaninate(15027-03-9)

Safety Data

• Hazardous Substances Data: 15027-03-9(Hazardous Substances Data)

Upstream product

• 2566-19-0 CbzGlyGly 
• 2577-90-4 methyl (2S)-2-amino-3-phenylpropanoate 
• 501-53-1 benzyl chloroformate 
• 13437-63-3 methyl [({[(benzyloxy)carbonyl]amino}acetyl)amino]acetate 
• 252846-38-1 Z-Gly-Gly-L-Phe-OCam 
• 169676-30-6 Z-Gly-Gly-L-Phe-OCH₂CF₃ 
• 186581-53-3 diazomethane 
• 13171-93-2 N-benzyloxycarbonyl-L-glycyl-L-glycyl-L-phenylalanine 

Downstream Products

• 2566-19-0 CbzGlyGly 
• 84969-56-2 Z-Gly-Gly-L-Phe-L-Leu-NH₂ 
• 60254-83-3 [des-tyr¹]-leucine enkephalin 
• 13171-93-2 N-benzyloxycarbonyl-L-glycyl-L-glycyl-L-phenylalanine 
• 113266-55-0 (S)-2-[2-(Benzyloxycarbonylamino-methyl)-thiazol-5-ylamino]-3-phenyl-propionic acid methyl ester 
• 79396-86-4 Boc-L-Tyr-Gly-Gly-L-Phe-L-Leu-NH₂ 
• 82948-92-3 [des-tyr¹]-leucine enkephalinamide 
• 81638-88-2 amide of N-t-butyloxycarbonyl-O-benzyl-L-tyrosylglycylglycyl-L-phenylalanyl-L-leucine 
• 113266-54-9 (S)-2-[2-(2-Benzyloxycarbonylamino-thioacetylamino)-thioacetylamino]-3-phenyl-propionic acid methyl ester 

Relevant articles and documents

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α-chymotrypsin-catalysed segment condensations via the kinetically controlled approach using carbamoylmethyl esters as acyl donors in organic media

The superiority of the carbamoylmethyl ester as an acyl donor for the α-chymotrypsin-catalysed segment condensations via the kinetically controlled approach is demonstrated in several model systems carried out in organic media with low water content. Furthermore, this approach is successfully applied to the construction of the Leu-enkephalin sequence via a 4 + 1 segment coupling.