1504-39-8

Basic information

• Product Name: 9-Anthracenecarboxylic acid methyl
• Synonyms: 9-Anthracenecarboxylic acid methyl;9-Anthracenecarboxylic acid methyl ester;Methyl 9-anthroate
• CAS NO: 1504-39-8
• Molecular Formula: C₁₆H₁₂O₂
• Molecular Weight: 236.27
• Mol File: 1504-39-8.mol
• Article Data: 16

Chemical Properties

• Boiling Point: 405.4°C at 760 mmHg
• Flash Point: 194.3°C
• Appearance: /
• Density: 1.208g/cm³
• Vapor Pressure: 8.81E-07mmHg at 25°C
• Refractive Index: 1.677
• CAS DataBase Reference: 9-Anthracenecarboxylic acid methyl(CAS DataBase Reference)
• NIST Chemistry Reference: 9-Anthracenecarboxylic acid methyl(1504-39-8)
• EPA Substance Registry System: 9-Anthracenecarboxylic acid methyl(1504-39-8)

Safety Data

• Hazardous Substances Data: 1504-39-8(Hazardous Substances Data)

Usage

General Description

9-Anthracenecarboxylic acid methyl is a chemical compound with the formula C15H12O2. It is a derivative of anthracene, a polycyclic aromatic hydrocarbon. Known for its fluorescent properties, 9-anthracenecarboxylic acid methyl is commonly used in organic synthesis and as a fluorescent probe in biological and environmental studies. It is also employed as a building block in the production of dyes, pigments, and pharmaceuticals. Due to its aromatic nature and potential toxicity, proper handling and disposal procedures should be followed when working with this compound.

InChI:InChI=1/C16H12O2/c1-18-16(17)15-13-8-4-2-6-11(13)10-12-7-3-5-9-14(12)15/h2-10H,1H3

Upstream product

• 16331-52-5 9-anthracenecarbonyl chloride 
• 91608-15-0 tris(2,4,6-trimethoxyphenyl)phosphine 
• 175407-20-2 anthracene-9-carbonyl fluoride 
• 67-56-1 methanol 
• 1468-95-7 9-hydroxymethylanthracene 
• 75-91-2 tert.-butylhydroperoxide 
• 642-31-9 9-anthracene aldehyde 
• 1564-64-3 9-Bromoanthracene 
• 79693-24-6 chlorure de methoxycarbonyl-10 anthracenediazonium-9 
• 723-62-6 anthracen-9-carboxylic acid 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 81795-34-8 6H,12H-5,12;6,11-di-o-benzeno-dibenzo[a,e]cyclooctene-5,11-dicarboxylic acid dimethyl ester 
• 159185-31-6 C₂₂H₁₈O₂ 
• 186581-53-3 diazomethane 

Downstream Products

• 89-43-0 methyl-N-3,7-dimethyl-7-hydroxyoctylidene anthranilate 

Relevant articles and documents

Dissymmetrical photodimerization of methyl 9-anthroate

Irradiation of methyl 9-anthroate through a Uranium filter gave the 1,4-10′,9′ and 1,4-9′,10′ cyclodimers as well as the 9,10-10′,9′ cyclodimer, this is the first example of intermolecular photodimerization involving the 1, 4, 9′, and 10′ positions of meso-substituted anthracenes. These dissymmetrical cyclodimers were found to be thermally more labile than the 9,10-10′,9′ cyclodimer.

Low-Temperature Emission Spectra of 9-Alkylanthracene Esters: Dimer Photodecomposition and Monomer Pair Interactions in Polymer Hosts

Effects due to variation in the alkyl chain length of photodimers of 9-alkylanthracene esters on their photodecomposition efficiencies at 12 K and, by implication, the photoproduct migration as a function of temperature within polymer hosts are investigated.It is shown that dimers with longer alkyl chains have a lower photodecomposition efficiency.The extent of photoproduct migration within the polymer following photodecomposition was also studied as a function of alkyl chain length.This migration and its modulation of the interaction between the separating monomers is shown to affect the emission spectrum.Thus, monomer migration was studied in temperature cycling experiments.It was also found, for the polymer hosts investigated - poly(methyl methacrylate), poly(vinyl chloride), and polystyrene - that these properties are host dependent.This result is probably due to the void space differences that exist among these polymers.

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A “universal” catalyst for aerobic oxidations to synthesize (hetero)aromatic aldehydes, ketones, esters, acids, nitriles, and amides

Functionalized (hetero)aromatic compounds are indispensable chemicals widely used in basic and applied sciences. Among these, especially aromatic aldehydes, ketones, carboxylic acids, esters, nitriles, and amides represent valuable fine and bulk chemicals, which are used in chemical, pharmaceutical, agrochemical, and material industries. For their synthesis, catalytic aerobic oxidation of alcohols constitutes a green, sustainable, and cost-effective process, which should ideally make use of active and selective 3D metals. Here, we report the preparation of graphitic layers encapsulated in Co-nanoparticles by pyrolysis of cobalt-piperazine-tartaric acid complex on carbon as a most general oxidation catalyst. This unique material allows for the synthesis of simple, functionalized, and structurally diverse (hetero)aromatic aldehydes, ketones, carboxylic acids, esters, nitriles, and amides from alcohols in excellent yields in the presence of air.

Pd-Colloids-Catalyzed/Ag2O-Oxidized General and Selective Esterification of Benzylic Alcohols

Palladium colloids obtained from the degradation of Hermann–Beller palladacycle proved to be an efficient catalytic system in combination with silver oxide as a selective oxidant for the oxidative esterification of differently substituted benzyl alcohols in MeOH as solvent. Excellent reactivity exhibited by the catalytic system also allowed the alcoholic coupling partner to be changed from MeOH to a wide range of alcohols having diverse functionalities. The mildness of the developed protocol also made it possible to employ propargyl alcohol as the coupling partner without any observation of any interference of the terminal alkyne. Selective oxidative coupling of a primary alcoholic functional group over secondary in the case of glycols and glycerols was also made possible using the developed catalyst system. To test the relevancy of Pd/Ag combined catalysis mixed Pd/Ag colloids were synthesized, characterized by TEM, XRD and XPS and applied to oxidative-esterification successfully.