Chemistry Letters p. 495 - 496 (1997)
Update date:2022-08-12
Topics:
Noh, Taehee
Lim, Heejun
Irradiation of methyl 9-anthroate through a Uranium filter gave the 1,4-10′,9′ and 1,4-9′,10′ cyclodimers as well as the 9,10-10′,9′ cyclodimer, this is the first example of intermolecular photodimerization involving the 1, 4, 9′, and 10′ positions of meso-substituted anthracenes. These dissymmetrical cyclodimers were found to be thermally more labile than the 9,10-10′,9′ cyclodimer.
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