1506-54-3Relevant articles and documents
Phase-selective solubility of poly(N-alkylacrylamide)s
Bergbreiter, David E.,Hughes, Reagan,Besinaiz, Jacqueline,Li, Chunmei,Osburn, Philip L.
, p. 8244 - 8249 (2003)
The extent of the phase-selective solubility of poly(N-alkylacrylamide)s was studied by UV-vis and fluorescence spectroscopy using poly(N-isopropylacrylamide) and poly(N-octadecylacrylamide) as representative polar and nonpolar poly(N-alkylacrylamide)s in a mixture of polar and nonpolar thermomorphic solvents. Phase-selective solubilities of greater than 10000:1 were seen with each labeled polymer in polar and nonpolar solvents such as heptane and DMF or heptane and 90% EtOH-H2O. Using a poly(N-acryloxysuccinimide) as a common precursor, a pool-split synthesis was devised to prepare a library of poly(N-alkylacrylamide)s whose members varied only in the size of their N-alkyl substituent. The solubilities of these library members were measured in both the polar and nonpolar phases of a thermomorphic heptane/90% EtOH-H2O mixture at 25°C. Such solvent mixtures are miscible hot (70°C) and biphasic cold (25°C). The results show that poly(N-pentylacrylamide) is selectively soluble (>99.5%) in the polar EtOH-rich phase at rest. Poly(N-alkylacrylamide)s with larger N-alkyl groups are predominantly (C6, 85%; C7, 95%) or exclusively (>C8, >99.5%) in the heptane-rich phase at rest.
Custom-designed Glycopolymer Syntheses by Terpolymerizations
Roy, Rene,Tropper, Francois D.,Romanowska, Anna
, p. 1611 - 1613 (1992)
Carbohydrate derivatives having lectin binding properties and bearing N-acryloyl functionality have been copolymerized under three-component terpolymerization conditions with acrylamide and N-acryloylated effector molecules to provide water-soluble glycopolymers with custom designed physico-chemical properties.
COMPOSITIONS, TREATING METHODS, AND TREATED FIBROUS SUBSTRATES
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Paragraph 0911, (2020/12/13)
Fluorine free compositions for treating fibrous substrates to make the fibrous substrates water repellent, method for treating the fibrous substrates with said compositions and water repellent fibrous substrates treated with said fluorine free compositions.
N-alkyl acrylamide intermediate and preparation method thereof and preparation method of N-alkyl acrylamide
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Paragraph 0159; 0165; 0166, (2017/01/26)
The invention belongs to the field of acrylamide, and particularly relates to an N-alkyl acrylamide intermediate and a preparation method thereof and a preparation method of N-alkyl acrylamide.The preparation method of N-alkyl acrylamide comprises the following steps that a cracking reaction is conducted on a compound with the structure of a formula (I) in the presence of a cracking catalyst, and N-alkyl acrylamide with the structure of a formula (VII) is obtained, wherein R1 and R2 are independently selected from alkyl, and n is larger than or equal to 0 and smaller than or equal to 30.The yield of N-alkyl acrylamide prepared through the method is high.It is indicated through experimental results that the total yield of N-alkyl acrylamide prepared through the method is larger than 85%.Please see the formulas in the description.