15101-69-6

Upstream product

• 5111-70-6 5-methoxy-1-indanone 
• 15101-68-5 1-phenyl-3-(3-(methoxy)phenyl)propan-1-one 
• 5470-91-7 3-methoxy-chalcone 
• 479213-87-1 1-(3-methoxyphenyl)-3-phenyl-2-propyn-1ol 
• 100-58-3 phenylmagnesium bromide 
• 7507-86-0 2-bromo-5-methoxy-benzaldehyde 
• 14900-39-1 phenylvinylboronic acid 

Downstream Products

• 15101-83-4 [2-(5-Methoxy-1-phenyl-indan-1-yl)-ethyl]-dimethyl-amine 
• 131003-31-1 5-methoxy-1-phenyl-1H-inden-2(3H)-one 
• 77605-58-4 2-Benzoyl-5-methoxyphenylacetic acid 
• 1334722-49-4 C₁₆H₁₄O₃ 
• 1334722-09-6 C₁₆H₁₂O₃ 
• 77605-64-2 2-Benzyl-5-methoxyphenylacetic Acid 

Relevant academic research and scientific papers

Catalytic Enantioselective [10+4] Cycloadditions

The first peri- and stereoselective [10+4] cycloaddition between catalytically generated amino isobenzofulvenes and electron-deficient dienes is described. The highly stereoselective catalytic [10+4] cycloaddition exhibits a broad scope with high yields,

Rhodium(II)- or Copper(I)-Catalyzed Formal Intramolecular Carbene Insertion into Vinylic C(sp2)?H Bonds: Access to Substituted 1H-Indenes

A rhodium(II)- or copper(I)-catalyzed formal intramolecular carbene insertion into vinylic C(sp2)?H bonds is reported herein. This method provides straightforward access to 1H-indenes with high efficiency and excellent functional-group compatibility. Mechanistically, the reaction is proposed to involve the following sequence: metal carbene formation, intramolecular nucleophilic addition of the double bond to the electron-deficient carbene carbon atom, dearomatization, and finally a 1,5-H shift.

Synthesis of substituted 4-aroyl-1-indanone and 5-aroyl-1-tetralone

Several substituted 4-aroyl-1-indanones 2 and 5-aroyl-1-tetralones 3 were prepared in good yields from 1-indanones 1 via a series of reasonable transformations.

Iodine/Et3SiH: A novel reagent system for the synthesis of 3-aryl-1H-indenes from 1,3-diaryl propargyl alcohols

1,3-Diaryl propargyl alcohols undergo smooth intramolecular Friedel-Crafts cyclization with triethylsilane in the presence of 10 mol % iodine 3-aryl-1H-indene derivatives in good yields in short reaction times. This is the first example on the synthesis of substituted indenes from 1,3-diaryl propargyl alcohols. The use of inexpensive and readily available molecular iodine makes this method quite simple, more convenient, and practical.