151071-01-1Relevant articles and documents
The synthesis of Plicatin B via the Heck reaction
Bates,Gabel
, p. 3547 - 3550 (1993)
The anti-microbial natural product Plicatin B has been synthesized in 53% overall yield using a Heck reaction as the key step. The optimum conditions for this reaction have been determined. Halophenols proved much less reactive than their corresponding ac
Synthesis of Phenolic Natural Products Using Palladium Catalyzed Coupling Reactions
Bates, Roderick W.,Gabel, Christine J.,Ji, Jianhua,Rama-Devi, Thota
, p. 8199 - 8212 (2007/10/02)
Derivatives of 2,4-diiodophenol are shown to undergo palladium catalyzed carbonylation and alkyne coupling reactions in excellent to moderate yield and high regioselectivity.The scope of these reactions is explored.Palladium catalyzed reactions are employ