15111-56-5

Basic information

• Product Name: 3-CYCLOHEXENE-1-CARBOXYLIC ACID ETHYL ESTER
• Synonyms: RARECHEM AL BI 0004;Ethyl 3-cyclohexencarboxylate;ETHYL 3-CYCLOHEXENE-1-CARBOXYLATE;3-CYCLOHEXENE-1-CARBOXYLIC ACID ETHYL ESTER;ethyl cyclohex-3-ene-1-carboxylate;3-CYCLOHEXENE-1-CARBOXYLIC ACID ETHYL ESTER 95+%;3-Cyclohexencarboxylate;3-Cyclhexene-1-carboxylic acid, ethyl ester
• CAS NO: 15111-56-5
• Molecular Formula: C9H14O2
• Molecular Weight: 154.21
• EINECS: 239-161-9
• Product Categories: Aromatic Esters;Esters;Ring Systems
• Mol File: 15111-56-5.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 195 °C
• Flash Point: 63°C
• Appearance: /
• Density: 0,99 g/cm3
• Vapor Pressure: 0.396mmHg at 25°C
• Refractive Index: 1.4550-1.4580
• CAS DataBase Reference: 3-CYCLOHEXENE-1-CARBOXYLIC ACID ETHYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: 3-CYCLOHEXENE-1-CARBOXYLIC ACID ETHYL ESTER(15111-56-5)
• EPA Substance Registry System: 3-CYCLOHEXENE-1-CARBOXYLIC ACID ETHYL ESTER(15111-56-5)

Safety Data

• Statements: 10
• Safety Statements: 16
• RIDADR: 3272
• Hazardous Substances Data: 15111-56-5(Hazardous Substances Data)

Usage

General Description

3-Cyclohexene-1-carboxylic acid ethyl ester is a chemical compound with the molecular formula C10H16O2. It is an ester, derived from the ethyl ester of cyclohexene carboxylic acid. 3-CYCLOHEXENE-1-CARBOXYLIC ACID ETHYL ESTER is commonly used in the production of various flavors and fragrances, as it imparts a fruity and floral odor. It is also utilized in the synthesis of pharmaceuticals and other organic compounds. In addition, 3-Cyclohexene-1-carboxylic acid ethyl ester has been studied for its potential antifungal and antibacterial properties, making it a valuable compound in the field of medicinal chemistry.

InChI:InChI=1/C9H14O2/c1-2-11-9(10)8-6-4-3-5-7-8/h3-4,8H,2,5-7H2,1H3

Upstream product

• 64-17-5 ethanol 
• 1165952-92-0 cyclohexa-1,4-diene 
• 3618-04-0 4-hydroxycyclohexyl carboxylic acid ethyl ester 
• 1228540-49-5 Ethyl (R)-3-cyclohexene-1-carboxylate 
• 5709-98-8 (R)-cyclohex-3-enecarboxylic acid 
• 18668-68-3 4-bromo-buta-1,2-diene 
• 140-88-5 ethyl acrylate 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 33035-71-1 Dispiro<5,1,5,1>tetradecan-3,11-dien-7,14-dion 
• 54639-69-9 1-(Cyclohex-3-enecarbonyl)-cyclohex-3-enecarboxylic acid ethyl ester 
• 932-67-2 cyclohex-3-enecarbonyl chloride 
• 106-99-0 buta-1,3-diene 

Downstream Products

• 5708-19-0 (1S)-3-cyclohexenecarboxylic acid 
• 67976-82-3 (1S)-3-cyclohexene-1-carboxylic acid (R)-(+)-α-methylbenzylamine salt 
• 4771-80-6 1,2,5,6-tetrahydrobenzoic acid 
• 1446143-42-5 4-(di(benzofuran-2-yl)(hydroxy)methyl)cyclohexane-1,2-diol 
• 1446143-41-4 di(benzofuran-2-yl)(cyclohex-3-enyl)methanol 
• 100-50-5 3-Cyclohexene-1-carboxaldehyde 
• 50552-13-1 Cyclohex-3-enylmethylnitrit 
• 134419-58-2 ethyl (1R*,3S*,4S*)-3-azido-4-hydroxycyclohexane-1-carboxylate 
• 81201-62-9 (d,l)-cis-3-phthalimidocyclohex-4-ene-1-carboxylic acid 
• 81202-29-1 (1R,5R)-5-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-cyclohex-3-enecarboxylic acid 
• 81202-30-4 (1S,5S)-5-(1,3-Dioxo-1,3-dihydro-isoindol-2-yl)-cyclohex-3-enecarboxylic acid 
• 81086-73-9 ethyl cis-5-phthalimidocyclohex-3-ene-1-carboxylate 
• 81131-40-0 (1S,3R)-3-aminocyclohexanecarboxylic acid 
• 81131-39-7 (+/-)-cis-3-Aminocyclohexanecarboxylic acid 

Relevant articles and documents

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METHOD FOR PURIFYING 4-HALO CYCLOHEXANE-1-CARBOXYLIC ACID, AND METHODS FOR PRODUCING PRODUCTS CONTAINING 4- HALO CYCLOHEXANE-1-CARBOXYLIC ACID

To provide a method for purifying a 4-halo cyclohexane-1-carboxylic acid which can be highly purified without performing column purification, and a method for producing a product containing the 4-halo cyclohexane-1-carboxylic acid.SOLUTION: There is provided a method for purifying a 4-halo cyclohexane-1-carboxylic acid comprising a crystallization step of subjecting a mixture including a 4-halo cyclohexane-1-carboxylic acid and a 3-halo cyclohexane-1-carboxylic acid to a crystallization operation in a mixed solvent of water and a water-soluble organic solvent or a hydrocarbon solvent to increase a content of the 4-halo cyclohexane-1-carboxylic acid.SELECTED DRAWING: None

Erbium triflate in ionic liquids: A recyclable system of improving selectivity in Diels-Alder reactions

The efficiency of Er(OTf)3 in promoting the Diels-Alder reactions between different dienes and dienophiles in ionic liquids has been investigated. Compared with the analogous cycloadditions performed in conventional solvents shorter reaction times are required to obtain good/excellent yields. In most cases an enhancement of regio- and endo:exo selectivity was observed. The role of the ionic liquid, as a function of the cationic part, i.e. the imidazolium based or the pyridinium based, is discussed well. The ILs containing the catalyst can be readily separated from the reaction products and recovered in very high purity for direct reuse, up to six cycles.

A practical new chiral controller for asymmetric Diels-Alder and alkylation reactions

(formula presented) The enantiomerically pure hydroxy sulfones (+)- and (-)-2 have been prepared from 1,2-epoxycyclohexane by a simple and practical procedure. The acrylate esters of these alcohols undergo BCl3-catalyzed Diels-Alder reactions with a variety of dienes at -78 to -55°C in CH2Cl2 or C7H8 with high dienophile face selectivity (Table 1). The chiral esters so formed are readily cleaved with recovery of the controllers (+)- or (-)-2. Esters of (+)- and (-)-2 can be converted to Z-polassium enolates and alkylated with high face selectivity.