151221-39-5

Basic information

• Product Name: Ethanone, 1-[6-[(1S)-1-hydroxyethyl]-2-pyridinyl]- (9CI)
• Synonyms: Ethanone, 1-[6-[(1S)-1-hydroxyethyl]-2-pyridinyl]- (9CI)
• CAS NO: 151221-39-5
• Molecular Formula: C₉H₁₁NO₂
• Molecular Weight: 165.18914
• Product Categories: ACETYLGROUP
• Mol File: 151221-39-5.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 276.5±25.0 °C(Predicted)
• Appearance: /
• Density: 1.137±0.06 g/cm3(Predicted)
• PKA: 13.12±0.20(Predicted)
• CAS DataBase Reference: Ethanone, 1-[6-[(1S)-1-hydroxyethyl]-2-pyridinyl]- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Ethanone, 1-[6-[(1S)-1-hydroxyethyl]-2-pyridinyl]- (9CI)(151221-39-5)
• EPA Substance Registry System: Ethanone, 1-[6-[(1S)-1-hydroxyethyl]-2-pyridinyl]- (9CI)(151221-39-5)

Safety Data

• Hazardous Substances Data: 151221-39-5(Hazardous Substances Data)

Upstream product

• 1129-30-2 2,6-Diacetylpyridine 
• 774225-86-4 1-[6-(1-hydroxyethyl)pyridin-2-yl]ethanone 
• 108-05-4 vinyl acetate 

Downstream Products

• 200337-71-9 2-[(S)-1-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-(2-methyl-[1,3]dioxolan-2-yl)-pyridine 1-oxide 
• 200337-70-8 2-[(S)-1-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-6-(2-methyl-[1,3]dioxolan-2-yl)-pyridine 
• 200337-69-5 1-{6-[(S)-1-(tert-Butyl-diphenyl-silanyloxy)-ethyl]-pyridin-2-yl}-ethanone 

Relevant articles and documents

Preparation of Highly Enantiopure Pyridylethanols by Baker's Yeast Reductions

Bakers' yeast is used to prepare 3a, 4a and 5a in high enantiomeric purity by addition of allyl alcohol to the reaction.The double reduction of 2,6-diacetylpyridine 2 with bakers' yeast leads to 5a with essentially complete enantiomeric purity predicted to be 99.97percentee.

Asymmetric synthesis catalyzed by transition metal complexes with new chiral ligands

A chiral ligand having the following structure: STR1 wherein AR is any aromatic and/or ring structure, and R is selected from the group consisting of aryl, oxygenated aryl, alkyl, oxygenated alkyl, AR, oxygenated AR and combinations thereof.

An efficient preparation of optically pure C2-symmetric aromatic diols by the asymmetric reduction of diacylaromatic compounds with B- chlorodiisopinocampheylborane

Asymmetric reduction of diacylaromatic compounds with B- chlorodiisopinocampheylborane provides the product diols in excellent diastereomeric and enantiomeric purity.