1512840-63-9Relevant academic research and scientific papers
Free-Radical-Promoted Copper-Catalyzed Intermolecular Cyanosulfonylation and Cyanotrifluoromethylation of Unactivated Alkenes in Water-Containing Solvents
Zhu, Yan,Tian, Jinlong,Gu, Xianfeng,Wang, Yonghui
, p. 13267 - 13275 (2018)
A novel and practical copper-catalyzed strategy for intermolecular cyanosulfonylation and cyanotrifluoromethylation of unactivated alkenes in water-containing solvents is described. The methodology developed provides an efficient and convenient access to a variety of β-sulfonyl nitriles and β-trifluoromethyl nitriles, which would have wide applications in chemical and pharmaceutical industries.
Copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes
He, Yu-Tao,Li, Lian-Hua,Yang, Yan-Fang,Zhou, Zhao-Zhao,Hua, Hui-Liang,Liu, Xue-Yuan,Liang, Yong-Min
, p. 270 - 273 (2014/01/23)
A novel and highly practical reaction for the copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes is presented here. This methodology provides a general and straightforward way to synthesize a variety of useful CF3-containing nitriles, which can be used for further preparation of pharmaceutically and agrochemically important compounds in synthetic organic chemistry.
