15129-96-1

Basic information

• Product Name: 2,2-Dimethyl-1,2-oxasilinan-6-one
• Synonyms: 2,2-Dimethyl-1,2-oxasilinan-6-one
• CAS NO: 15129-96-1
• Molecular Formula: C₆H₁₂O₂Si
• Molecular Weight: 144.24
• Mol File: 15129-96-1.mol
• Article Data: 2

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2,2-Dimethyl-1,2-oxasilinan-6-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-Dimethyl-1,2-oxasilinan-6-one(15129-96-1)
• EPA Substance Registry System: 2,2-Dimethyl-1,2-oxasilinan-6-one(15129-96-1)

Safety Data

• Hazardous Substances Data: 15129-96-1(Hazardous Substances Data)

Upstream product

• 14857-26-2 but-3-enoic acid dimethylsilanyl ester 
• 24337-18-6 4,4'-(1,1,3,3-tetramethyl-disiloxane-1,3-diyl)-bis-butyric acid bis-trimethylsilanyl ester 
• 18156-15-5 (3-cyanopropyl)dimethylsilyl chloride 
• 1066-35-9 dimethylmonochlorosilane 
• 13688-54-5 3-butenoictrimethylsilylester 
• 2345-40-6 4-trimethylsilanyl-butyric acid 

Downstream Products

• 96-48-0 4-butanolide 
• 3353-68-2 4,4'-(1,1,3,3-tetramethyldisiloxane-1,3-diyl)dibutyric acid 

Relevant articles and documents

Highly regioselective intramolecular hydroxymethylation of α,β-unsaturated carboxylic acids

A convenient synthesis of hydroxy esters 7 and lactones 8 by starting from easily available α,β-unsaturated carbocylic acids 4 is described. The key step of this transformation is a hitherto unknown radical cyclization of silyl esters, which exhibits a high degree of regioselectivity through steric and orbital control.