153172-73-7Relevant academic research and scientific papers
Expedited palladium-catalyzed amination of aryl nonaflates through the use of microwave-irradiation and soluble organic amine bases
Tundel, Rachel E.,Anderson, Kevin W.,Buchwald, Stephen L.
, p. 430 - 433 (2007/10/03)
Microwave-assisted, palladium-catalyzed C-N bond-forming reactions with aryl/heteroaryl nonaflates and amines using the soluble amine bases DBU (1,8-diazabicyclo[5.4.0]undec-7-ene) or MTBD (7-methyl-1,5,7-triazabicyclo[4.4. 0]dec-5-ene) and ligands (1-3) resulted in good to excellent yields (71-99%) of arylamines in short reaction times (1-45 min).
Anchimeric Assistance in the Specific Acid-catalyzed Hydration of Benzonitriles
Smyth, Richard M.,Williams, Andrew
, p. 2171 - 2174 (2007/10/02)
2-(Acylamido)benzonitriles react to give exclusively the corresponding 2-(acylamido)benzamides under relatively mild aqueous acid conditions.The kinetics for hydration at 50 deg C in aqueous HCl with ionic strength kept at 1 mol dm-3 with KCl o
