153215-67-9

Upstream product

• 350255-13-9 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose 
• 100-39-0 benzyl bromide 
• 39682-04-7 (3aR,5S,6R,6aR)-6-(benzyloxy)-2,2-dimethyltetrahydrofuran[2,3-d][1,3]dioxolane-5-carboxylic acid 
• 153237-94-6 Acetic acid (S)-((3aR,5S,6S,6aR)-6-benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-((4R,5R,6R)-4,5-bis-triisopropylsilanyloxy-6-triisopropylsilanyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-methyl ester 
• 153237-93-5 (S)-((3aR,5R,6S,6aR)-6-Benzyloxy-2,2-dimethyl-tetrahydro-furo[2,3-d][1,3]dioxol-5-yl)-((4R,5R,6R)-4,5-bis-triisopropylsilanyloxy-6-triisopropylsilanyloxymethyl-5,6-dihydro-4H-pyran-2-yl)-methanol 
• 23558-05-6 3-O-benzyl-1,2-O-isopropylidene-1,5-D-xylo-dialdofuranose 
• 591727-19-4 1-2,5-6 di-O-isopropylidene 3-O-benzyl α(D)gluco-pentoaldofuranose 
• 50-99-7 D-glucose 

Downstream Products

• 277752-54-2 1,2-O-Isopropylidene-3-O-benzyl-6-deoxy-6-diazo-α-D-xylo-hexo-furan-5-ulose 
• 951250-91-2 (-)-(3R,4R,6R,7R,8R)-8-benzyloxy-6,7-O-isopropylidene-2,3-diphenyl-5-oxa-2-aza-spiro[3.4]octan-1-one 

Relevant academic research and scientific papers

NOVEL SPIROBICYCLIC INTERMEDIATES

The present invention relates to novel spirobicyclic intermediates useful in the synthesis of spirobicyclic nucleoside analogues.

Stereoselective synthesis of spiro-β-lactams using d-(+)-glucose derived chiral pool: remarkable influence of the torquoelectronic effect

Diastereoselective synthesis of spiro-β-lactams via [2+2] cycloaddition reaction of imines and chiral ketenes is described. The chiral ketene was prepared from commercially available, inexpensive d-glucose. Although, theoretically four diastereomers are p

Synthesis of C1-C6 segment of carbonolide B: Wolff rearrangement of sugar α-diazo ketones

Silver benzoate catalysed Wolff rearrangement of a series of α-diazo ketones, derived from furanuronic acids, in methanol proceeds with good yields to produce the corresponding one carbon homologated methyl-5-deoxy- hexo-furanuronate. The utility of methy

Towards the synthesis of the squalestatins/zaragozic acids: Synthesis of an advanced intermediate and introduction of the C-1 sidechain

A highly convergent synthesis of a squalestatin/zaragozic acid A C-4-decarboxydeoxy intermediate has been achieved. The key step involves the construction of the C-1-C-1′ bond by the addition of a fully functionalized C-1 sidechain anion (derived from iod

Short Synthetic Route to Congeners of the Undecose Antibiotic Herbicidin

The undecose backbone of the herbicidins has been assemled via direct alkylation, hydroxyalkylation, or acylation of the cyclic vinylanion 5 with the xylofuranose triflate 14, aldehyde 6, or acid chloride 10, respectively.