153361-01-4

Basic information

• Product Name: 2-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-
• CAS NO: 153361-01-4
• Molecular Formula: C22H28O2Si
• Molecular Weight: 352.549
• Mol File: 153361-01-4.mol

Chemical Properties

• CAS DataBase Reference: 2-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-(153361-01-4)
• EPA Substance Registry System: 2-Hexenal, 6-[[(1,1-dimethylethyl)diphenylsilyl]oxy]-, (2E)-(153361-01-4)

Safety Data

• Hazardous Substances Data: 153361-01-4(Hazardous Substances Data)

Upstream product

• 176907-54-3 (E)-Methyl 6-(tert-butyldiphenylsilyloxy)hex-2-enoate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 130372-07-5 4-(tret-butyldiphenylsilyloxy)butan-1-ol 
• 111649-71-9 (E)-6-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)hex-2-en-1-ol 
• 127793-62-8 4-((tert-butyldiphenylsilyl)oxy)butanal 
• 2136-75-6 (triphenylphosphoranylidene)acetaldehyde 

Downstream Products

• 869226-99-3 10-(tert-butyl(diphenyl)silanyloxy)-5-hydroxy-3-oxo-dec-6-enoic acid methyl ester 
• 180866-32-4 (7E,9E)-(R)-13-(tert-Butyl-diphenyl-silanyloxy)-7-methyl-trideca-1,7,9-trien-4-ol 
• 182953-78-2 (4E,6E)-2-Benzenesulfonyl-10-(tert-butyl-diphenyl-silanyloxy)-4-methyl-deca-4,6-dienenitrile 
• 180866-34-6 tert-Butyl-((4E,6E)-(R)-10-methoxy-7-methyl-trideca-4,6,12-trienyloxy)-diphenyl-silane 
• 180866-33-5 (4E,6E)-10-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-deca-4,6-dienal 
• 182953-79-3 (4E,6E)-10-(tert-Butyl-diphenyl-silanyloxy)-4-methyl-deca-4,6-dienenitrile 
• 155233-30-0 curacin A 
• 314021-43-7 {5-[6-(2-benzenesulfonyl-ethyl)-6-methoxy-3,6-dihydro-2H-pyran-2-yl]-pent-4-enyloxy}-tert-butyl-diphenyl-silane 
• 314021-30-2 (E)-(S)-1-Benzenesulfonyl-12-(tert-butyl-diphenyl-silanyloxy)-7-triethylsilanyloxy-dodec-8-en-4-yn-3-one 
• 314021-42-6 (4Z,8E)-(S)-1-Benzenesulfonyl-12-(tert-butyl-diphenyl-silanyloxy)-7-triethylsilanyloxy-dodeca-4,8-dien-3-one 
• 314021-29-9 C₃₁H₄₆O₂Si₂ 

Relevant articles and documents

Palladium- and copper-catalyzed 1,4-additions of organozinc compounds to conjugated aldehydes

Conjugated aldehydes undergo smooth Pd(OAc)2·PPh 3- or Me2CuCNLi2-catalyzed 1,4-addition of dialkylzinc reagents.

Studies Directed toward the Total Synthesis of Azaspiracid: Stereoselective Construction of C1-C12, C13-C19, and C21-C25 Fragments

equation presented The efficient entry to the C1-C12, C13-C19, and C21-C25 fragments of azaspiracid is outlined. The C1-C12 portion is constructed using a key asymmetric allenyl borane addition to the corresponding α,β-unsaturated aldehyde. The synthesis of the C13-C19 portion utilizes an Evans asymmetric alkylation followed by Sharpless asymmetric dihydroxylation. In addition, a novel solution to the mismatched effects of a neighboring chiral oxazolidinone during a Sharpless dihydroxylation is detailed.

Radical-Induced Fragmentations of Ketoepoxides

The cleavage of α-ketoepoxycarbinyl radicals has been investigated for six substrates using two methods of radical formation.Products resulting from carbon-oxygen bond cleavage were observed in each case, but vinyl ethers derived from epoxide carbon-carbon cleavage were isolated in one case.