176907-54-3

Basic information

• Product Name: (E)-Methyl 6-(tert-butyldiphenylsilyloxy)hex-2-enoate
• Synonyms: (E)-Methyl 6-(tert-butyldiphenylsilyloxy)hex-2-enoate
• CAS NO: 176907-54-3
• Molecular Weight: 382.575
• Mol File: 176907-54-3.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (E)-Methyl 6-(tert-butyldiphenylsilyloxy)hex-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-Methyl 6-(tert-butyldiphenylsilyloxy)hex-2-enoate(176907-54-3)
• EPA Substance Registry System: (E)-Methyl 6-(tert-butyldiphenylsilyloxy)hex-2-enoate(176907-54-3)

Safety Data

• Hazardous Substances Data: 176907-54-3(Hazardous Substances Data)

Upstream product

• 311-46-6 ethyl 2-(dimethoxyphosphoryl)acetate 
• 127793-62-8 4-((tert-butyldiphenylsilyl)oxy)butanal 
• 5927-18-4 trimethyl phosphonoacetate 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 130372-07-5 4-(tret-butyldiphenylsilyloxy)butan-1-ol 
• 21204-67-1 methyl (triphenylphosphoranylidene)acetate 

Downstream Products

• 176907-57-6 (E)-6-(2-Nitrophenoxy)hex-4-enol 
• 176907-60-1 (E)-6-(2-Aminophenoxy)hex-4-enol 
• 167102-88-7 2-[(6-tert-butyldiphenylsilyloxy)hex-2-enyloxy]iodobenzene 
• 167102-90-1 2-[(6-methanesulfonyloxy)hex-2-enyloxy]iodobenzene 
• 167102-91-2 2-[(6-azido)hex-2-enyloxy]iodobenzene 
• 167102-89-8 2-[(6-hydroxy)hex-2-enyloxy]iodobenzene 
• 314021-43-7 {5-[6-(2-benzenesulfonyl-ethyl)-6-methoxy-3,6-dihydro-2H-pyran-2-yl]-pent-4-enyloxy}-tert-butyl-diphenyl-silane 
• 153361-01-4 6-(tert-butyl(diphenyl)silanyloxy)-hex-2-enal 
• 314021-30-2 (E)-(S)-1-Benzenesulfonyl-12-(tert-butyl-diphenyl-silanyloxy)-7-triethylsilanyloxy-dodec-8-en-4-yn-3-one 
• 314021-42-6 (4Z,8E)-(S)-1-Benzenesulfonyl-12-(tert-butyl-diphenyl-silanyloxy)-7-triethylsilanyloxy-dodeca-4,8-dien-3-one 
• 314021-29-9 C₃₁H₄₆O₂Si₂ 
• 314021-28-8 (E)-(S)-9-(tert-Butyl-diphenyl-silanyloxy)-non-5-en-1-yn-4-ol 
• 111649-71-9 (E)-6-(2,2-dimethyl-1,1-diphenyl-1-silapropoxy)hex-2-en-1-ol 

Relevant articles and documents

Studies Directed toward the Total Synthesis of Azaspiracid: Stereoselective Construction of C1-C12, C13-C19, and C21-C25 Fragments

equation presented The efficient entry to the C1-C12, C13-C19, and C21-C25 fragments of azaspiracid is outlined. The C1-C12 portion is constructed using a key asymmetric allenyl borane addition to the corresponding α,β-unsaturated aldehyde. The synthesis of the C13-C19 portion utilizes an Evans asymmetric alkylation followed by Sharpless asymmetric dihydroxylation. In addition, a novel solution to the mismatched effects of a neighboring chiral oxazolidinone during a Sharpless dihydroxylation is detailed.

Intramolecular termination of radical-polar crossover reactions

Cyclic ethers result from intramolecular trapping of cations formed through the radical-polar crossover process.