1534-27-6

Basic information

• Product Name: 3-DODECANONE
• Synonyms: ETHYL N-NONYL KETONE;3-DODECANONE;dodecanone;Dodecanone-(3);Ethyl nonyl ketone;dodecan-3-one;3-DODECANONE 98+%
• CAS NO: 1534-27-6
• Molecular Formula: C12H24O
• Molecular Weight: 184.32
• EINECS: 216-254-2
• Mol File: 1534-27-6.mol
• Article Data: 16

Chemical Properties

• Melting Point: 19.43°C
• Boiling Point: 134 °C / 18mmHg
• Flash Point: 19 °C
• Appearance: /
• Density: 0.83
• Vapor Pressure: 0.0315mmHg at 25°C
• Refractive Index: 1.4323 (estimate)
• CAS DataBase Reference: 3-DODECANONE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-DODECANONE(1534-27-6)
• EPA Substance Registry System: 3-DODECANONE(1534-27-6)

Safety Data

• Safety Statements: S24/25:Avoid contact with skin and eyes.
• Hazardous Substances Data: 1534-27-6(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 2907, 1978 DOI: 10.1021/jo00408a034

InChI:InChI=1/C12H24O/c1-3-5-6-7-8-9-10-11-12(13)4-2/h3-11H2,1-2H3

Upstream product

• 97029-79-3 1-hydroxydodecan-3-one 
• 10203-30-2 dodecan-3-ol 
• 111-83-1 1-bromo-octane 
• 6125-75-3 N-cyclohexylbutylidene-2-imine 
• 89638-16-4 ethyl 2-(diphenylmethylsilyl)decanoate 
• 75-03-6 ethyl iodide 
• 4282-42-2 1-iodononane 
• 79-03-8 propionyl chloride 
• 112-13-0 n-decanoyl chloride 
• 121-44-8 triethylamine 
• 124-11-8 non-1-ene 
• 112-12-9 methyl nonyl ketone 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 10467-10-4 ethylmagnesium iodide 

Downstream Products

• 10203-30-2 dodecan-3-ol 
• 17312-57-1 3-methyldodecane 

Relevant articles and documents

Hydroformylation of alkenes using heterogeneous catalyst prepared by intercalation of HRh(CO)(TPPTS)3 complex in hydrotalcite

Intercalation of HRh(CO)(TPPTS)3 complex into the interlayer space of hydrotalcite was carried out to prepare an eco-friendly heterogeneous hydroformylation catalyst. Intercalated catalyst was characterized by 31P NMR, P-XRD, FT-IR, SEM and surface area measurements. Catalytic activity of intercalated catalyst [HT(3.5)-INT] was evaluated for hydroformylation of linear alkenes of varied carbon number from C5 to C13 as well as cyclic alkenes. Selectivity of the aldehydes was observed to decrease with increase in the carbon chain length of linear alkenes. Effect of reaction parameters on catalytic activity of intercalated catalyst was studied by varying the catalyst amount, 1-hexene concentration, reaction temperature, partial pressure of carbon monoxide and hydrogen for hydroformylation of 1-hexene. The catalyst was re-cycled up to five times without significant loss in the alkene conversion and selectivity of aldehydes.

Copper-catalysed aerobic oxidation of alcohols using fluorous biphasic catalysis

A copper(I) catalysed and TEMPO mediated fluorous biphasic oxidation of primary, secondary, allylic and benzylic alcohols with oxygen in the presence of a bipyridine ligand bearing perfluorinated ponytails is described. High chemoselectivities are observed in the oxidation of substituted cyclohexanols (substituted axial cyclohexanols react 6-8 times faster than the corresponding equatorial cyclohexanols).

Tetramethylethylenediammonium dichromate (TMEDADC): A new selective oxidation reagent

TMEDADC obtained from Chromium trioxide and TMEDA has been conveniently utilized for the selective oxidation of benzylic and allylic alcohols in excellent yield for the first time.