154108-97-1

Basic information

• Product Name: (S)-3-Acetyl-2-tert-butoxycarbonylamino-4-[(E)-hydroxyimino]-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
• Synonyms: (S)-3-Acetyl-2-tert-butoxycarbonylamino-4-[(E)-hydroxyimino]-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS NO: 154108-97-1
• Molecular Weight: 426.554
• Mol File: 154108-97-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-3-Acetyl-2-tert-butoxycarbonylamino-4-[(E)-hydroxyimino]-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-3-Acetyl-2-tert-butoxycarbonylamino-4-[(E)-hydroxyimino]-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(154108-97-1)
• EPA Substance Registry System: (S)-3-Acetyl-2-tert-butoxycarbonylamino-4-[(E)-hydroxyimino]-pentanoic acid (1R,2S,5R)-2-isopropyl-5-methyl-cyclohexyl ester(154108-97-1)

Safety Data

• Hazardous Substances Data: 154108-97-1(Hazardous Substances Data)

Upstream product

• 63254-60-4 (1R,2S,5R)-2-isopropyl-5-methylcyclohexyl 2-aminoacetate 
• 7377-98-2 (-)-menthyl chloroacetate 
• 145280-09-7 (1R,2S,5R)-2-(1-methylethyl)-5-methylcyclohexyl 2-<(tert-butoxycarbonyl)amino>bromoacetate 
• 145280-11-1 (1R,2S,5R)-2-(1-methylethyl)-5-methylcyclohexyl 2-<(tert-butoxycarbonyl)amino>acetate 
• 2216-51-5 (-)-menthol 
• 154108-95-9 (1R,3R,4S)-menthyl (2S)-N-t-BOC-3-acetyl-4-oxonorvaline 

Relevant articles and documents

A radical-organometallic glycine synthon. Preparation of homochiral heterocyclic α-amino acids

Co(Acac)2 reacts with (1) and (d)-menthyl N-BOC-2-bromoglycinates to give (1)- and (d)-menthyl N-BOC-3-acetylnorvalinates, which are converted into homochiral 2-(3,5-dimethyl-4-pyrazolyl)glycine and 2-(3,5-dimethyl)-4-isoxazolylglycine.