154307-85-4

Upstream product

• 14398-40-4 (E)-2-methyl-4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butenal 
• 121693-79-6 (E)-tert-butyldimethyl-((3-methylpent-2-en-4-yn-1-yl)oxy)silane 

Downstream Products

• 154307-86-5 Benzoic acid (E)-6-(tert-butyl-dimethyl-silanyloxy)-4-methyl-1-[(E)-1-methyl-3-(2,6,6-trimethyl-cyclohex-1-enyl)-propenyl]-hex-4-en-2-ynyl ester 
• 210700-51-9 ((2E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethylcyclohex-1-enyl)nona-2,6,8-trien-4-ynyloxy)(tert-butyl)dimethylsilane 
• 210700-50-8 tert-butyldimethylsilyl (7E,9Z,11Z,13E)-12-(phenylsulfinyl)retinyl ether 
• 68-26-8 9-cis-retinol 
• 302-79-4 9-cis-retinoic acid 
• 210700-52-0 tert-butyldimethylsilyl (7E,9Z,11E,13E)-retinyl ether 
• 29444-25-5 (9Z,13Z)-retinol 
• 302-79-4 9,13-di-cis-retinoic acid 

Relevant academic research and scientific papers

Unidirectional thermal electrocyclic ring forming reactions of methylenecyclobutenes from vinylallenes in the retinoid series

A unidirectional, regiospecific formation of methylenecyclobutenes from substituted divinylallenes related to the 11,7-retroretinoids has been found at temperatures considerably lower than the parent system. Kinetic data are reported for the examples stud

Structural effects affecting the thermal electrocyclic ring closure of vinylallenes to alkylidenecyclobutenes

The thermal electrocyclic ring closure of (2E,7E)-3,4,7-trialkylnona-2,4,5,7-tetraenes (divinyl-4,5-allenes) is regioselective, occurring at the most sterically congested vinylallene subunit to afford the trisubstituted alkylidenecyclobutene. Ring closure