154307-85-4

Basic information

• Product Name: (2E,7E)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,7-dien-5-yn-4-ol
• Synonyms: (2E,7E)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,7-dien-5-yn-4-ol
• CAS NO: 154307-85-4
• Molecular Weight: 416.72
• Mol File: 154307-85-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2E,7E)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,7-dien-5-yn-4-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (2E,7E)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,7-dien-5-yn-4-ol(154307-85-4)
• EPA Substance Registry System: (2E,7E)-9-(tert-Butyl-dimethyl-silanyloxy)-3,7-dimethyl-1-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,7-dien-5-yn-4-ol(154307-85-4)

Safety Data

• Hazardous Substances Data: 154307-85-4(Hazardous Substances Data)

Upstream product

• 14398-40-4 (E)-2-methyl-4-(2,6,6-trimethyl-1-cyclohexenyl)-2-butenal 
• 121693-79-6 (E)-tert-butyldimethyl-((3-methylpent-2-en-4-yn-1-yl)oxy)silane 

Downstream Products

• 210700-51-9 ((2E,6E,8E)-3,7-dimethyl-9-(2,6,6-trimethylcyclohex-1-enyl)nona-2,6,8-trien-4-ynyloxy)(tert-butyl)dimethylsilane 
• 210700-50-8 tert-butyldimethylsilyl (7E,9Z,11Z,13E)-12-(phenylsulfinyl)retinyl ether 
• 302-79-4 9,13-di-cis-retinoic acid 
• 29444-25-5 (9Z,13Z)-retinol 

Relevant articles and documents

Unidirectional thermal electrocyclic ring forming reactions of methylenecyclobutenes from vinylallenes in the retinoid series

A unidirectional, regiospecific formation of methylenecyclobutenes from substituted divinylallenes related to the 11,7-retroretinoids has been found at temperatures considerably lower than the parent system. Kinetic data are reported for the examples stud