Tetrahedron Letters p. 6293 - 6296 (1993)
Update date:2022-07-30
Topics: Vinylallenes Unidirectional Thermal electrocyclic ring forming reactions Methylenecyclobutenes Retinoid series
Rey, Jose Garcia
Rodriguez, Jesus
De Lera, Angel R.
A unidirectional, regiospecific formation of methylenecyclobutenes from substituted divinylallenes related to the 11,7-retroretinoids has been found at temperatures considerably lower than the parent system. Kinetic data are reported for the examples stud
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