154558-90-4

Basic information

• Product Name: Benzothiazole, 6-chloro-2-(4-methoxyphenyl)-
• CAS NO: 154558-90-4
• Molecular Formula: C14H10ClNOS
• Molecular Weight: 275.759
• Mol File: 154558-90-4.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Benzothiazole, 6-chloro-2-(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzothiazole, 6-chloro-2-(4-methoxyphenyl)-(154558-90-4)
• EPA Substance Registry System: Benzothiazole, 6-chloro-2-(4-methoxyphenyl)-(154558-90-4)

Safety Data

• Hazardous Substances Data: 154558-90-4(Hazardous Substances Data)

Upstream product

• 127351-02-4 N-(4-chlorophenyl)-4-methoxybenzothioamide 
• 118063-94-8 2,6-Dichloro-2λ⁴-benzo[1,2,3]dithiazole 
• 106-47-8 4-chloro-aniline 
• 123-11-5 4-methoxy-benzaldehyde 
• 2942-10-1 6-chloro-1,3-benzothiazole 
• 696-62-8 para-iodoanisole 
• 1612227-95-8 N-(4-chloro-2-iodophenyl)-4-methoxybenzothioamide 
• 7595-61-1 N-(4-chlorophenyl)-4-methoxybenzamide 
• 3292-54-4 6-chloro-3H-benzo[d][1,2,3]dithiazole 2-oxide 
• 23474-98-8 2-amino-5-chlorobenzenethiol 
• 3672-47-7 3-oxo-3-(4'-methoxyphenyl)propanenitrile 
• 31183-89-8 2-[(2-amino-5-chlorophenyl)dithio]-4-chlorophenylamine 

Downstream Products

• 1379479-43-2 6-chloro-2-(5-methoxy-4'-methyl-[1,1'-biphenyl]-2-yl)benzo[d]thiazole 
• 1379479-38-5 6-chloro-2-(5'-methoxy-4,4''-dimethyl-[1,1':3',1''-terphenyl]-2'-yl)benzo[d]thiazole 
• 1379479-39-6 6-chloro-2-(5'-methoxy-[1,1':3',1''-terphenyl]-2'-yl)benzo[d]thiazole 

Relevant articles and documents

Green and highly efficient synthesis of 2-arylbenzothiazoles using glycerol without catalyst at ambient temperature

A one-pot and clean synthesis of 2-arylbenzothiazoles via the ambient temperature reaction of 2-aminothiophenols and aromatic aldehydes without catalyst in glycerol as a green solvent has been reported. 2012 by the Authors.

Room temperature HFIP/Ag-promoted palladium-catalyzed C–H functionalization of benzothiazole with iodoarenes

A versatile synthetic protocol involving the room temperature direct arylation of benzothiazole with a wide variety of iodoarenes under Ag-promoted Pd-catalyzed conditions in HFIP as the reaction solvent has been presented. A sequential HFIP-promoted sele

Organocatalytic syntheses of benzoxazoles and benzothiazoles using aryl iodide and oxone via C-H functionalization and C-O/S bond formation

An organocatalytic protocol for the syntheses of 2-substituted benzoxazoles and benzothiazoles is described from alkyl-/arylanilides and alkyl-/arylthioanilides using 1-iodo-4-nitrobenzene as catalyst and oxone as an inexpensive and environmentally safe terminal oxidant at room temperature in air via oxidative C-H functionalization and C-O/S bond formation. The procedure is simple and general and provides an effective route for the construction of functionalized 2-alkyl-/arylbenzoxazoles and 2-alkyl-/arylbenzothiazoles with moderate to high yields. The synthetic and mechanistic aspects have been described.