15462-16-5

Basic information

• Product Name: Tridecanoic acid, 13-bromo-
• Synonyms: 13-Brom-tridecylsaeure;Tridecanoic acid,13-bromo;13-Bromtridecansaeure;13-bromo-tridecanoic acid
• CAS NO: 15462-16-5
• Molecular Formula: C13H25BrO2
• Molecular Weight: 293.244
• Mol File: 15462-16-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Tridecanoic acid, 13-bromo-(CAS DataBase Reference)
• NIST Chemistry Reference: Tridecanoic acid, 13-bromo-(15462-16-5)
• EPA Substance Registry System: Tridecanoic acid, 13-bromo-(15462-16-5)

Safety Data

• Hazardous Substances Data: 15462-16-5(Hazardous Substances Data)

Upstream product

• 1611-56-9 1-Bromo-11-hydroxyundecane 
• 105-53-3 diethyl malonate 
• 112-86-7 cis-13-docosenoic acid 
• 505-52-2 brassylic acid 
• 1472-87-3 dimethyl 1,11-undecanedicarboxylate 
• 996-82-7 sodium diethylmalonate 
• 116754-58-6 13-bromo-1-tridecylalcohol 
• 5675-51-4 1,12-dodecandiol 
• 65157-88-2 13-oxotridecanoic acid 
• 13362-52-2 1,13-tridecanediol 
• 503154-44-7 13-bromotridecanenitrile 
• 3344-77-2 12-bromododecanol 
• 151-50-8 potassium cyanide 
• 7735-38-8 13-hydroxytridecanoic acid 

Downstream Products

• 945226-22-2 C₄₇H₈₉N₃O₈ 
• 4568-88-1 (S)-15,16-dihydroxy-hexadecanoic acid methyl ester 
• 14502-46-6 ω-tridecyn-1-oic acid 
• 29780-00-5 methyl 12-tridecenoate 
• 56909-01-4 12-tridecynoic acid methyl ester 
• 108545-37-5 13-(2-Nitro-phenylselanyl)-tridecanoic acid methyl ester 
• 693-71-0 (13Z)-octadec-13-enoic acid 
• 77798-78-8 2,5-Bis(13-bromtridecanoylamino)-3,6-bis<12-(tetrahydro-2-pyranyloxy)dodecyl>hydrochinon-dimethylether 
• 77798-76-6 2,5-Bis(13-bromtridecanoylamino)-3,6-bis<(11-methoxycarbonyl)undecyl>hydrochinon-dimethylether 
• 77798-77-7 2,5-Bis(13-bromtridecanoylamino)-3,6-bis(11-carboxyundecyl)hydrochinon-dimethylether 
• 77798-79-9 2,5-Bis(13-bromtridecanoylamino)-3,6-dioctylhydrochinon-dimethylether 

Relevant articles and documents

Chemical synthesis of diglucosyl diacylglycerols utilizing glycosyl donors with stereodirecting cyclic silyl protective groups

Chemical syntheses of the bacterial diglucosyl diacylglycerols 1-heptadecanoyl-2-pentadecanoyl-3-O-[6-O-(β-d-glucopyranosyl)-β-d-glucopyranosyl]-sn-glycerol and 1-(cis-13-octadecenoyl)-2-palmitoyl-3-O-[2-O-(α-d-glucopyranosyl)-α-d-glucopyranosyl]-sn-glycerol are described. The syntheses feature the stereoselective construction of glycosidic linkages in glycosylation reaction by utilizing glycosyl donors with stereodirecting cyclic silyl protective groups. The 1,1,3,3-tetraisopropyldisiloxane-1,3-diyl (TIPDS) group was used for formation of the β-glycosidic linkage, while the di-tert-butylsilylene (DTBS) group was used for α-linkage formation. The silyl protective groups were chemoselectively cleavable without affecting acyl functionalities on the glycerol moiety and proved effective for the synthesis of diacylglycoglycerolipids.

Annonaceous acetogenin mimics bearing a terminal lactam and their cytotoxicity against cancer cells

Annonaceous acetogenins are a large class of naturally occurring polyketides exhibiting potent anticancer activities. Based on our previous discovery of AA005, a multi-ether mimic of natural acetogenins having potent antitumor activities and significant selectivity between normal cells and cancer cells, a new series of mimics containing a terminal lactam were designed, synthesized and evaluated. Bioactivity study against cancer cells shows that the N-methylated lactam-containing compounds 3, 4, and 5 exhibit comparable potencies to that of AA005, as well as the similar selectivity to cancer cells. Hydrocarbon-length effects of N-alkyl were further explored through synthesizing derivatives 24-26, and application of this derivation protocol to the fluorescent labeling was also investigated.