155430-52-7Relevant academic research and scientific papers
Highly stereoselective epoxidation of a 4-methyl-5- (triethylsilyl)oxyallyl alcohol system with m-chloroperoxybenzoic acid
Maruyama, Kimiyuki,Ueda, Masato,Sasaki, Shinobu,Iwata, Yasuhiro,Miyazawa, Masahiro,Miyashita, Masaaki
, p. 4517 - 4520 (2007/10/03)
Epoxidation of 4-methyl-5-(triethylsilyl)oxyallyl alcohol system with m- chloroperoxybenzoic acid (MCPBA) has been found to occur highly stereoselectively and in high yields from the opposite side of the C5 triethylsilyloxy group regardless of
Synthetic Studies on Polypropionate Antibiotics Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum. A Highly Stereoselective Construction of the Eight Contiguous Chiral Centers of Ansa-chains of Rifamycins
Miyashita, Masaaki,Yoshihara, Kousei,Kawamine, Katsumi,Hoshino, Masahide,Irie, Hiroshi
, p. 6285 - 6288 (2007/10/02)
A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed
