155430-54-9

Upstream product

• 3282-30-2 pivaloyl chloride 
• 155430-53-8 (3S,4R,5R,6S,7R,8R,9S,10S)-11-Benzyloxy-4,6,8,10-tetramethyl-5,7,9-tris-triethylsilanyloxy-undecane-1,3-diol 
• 79027-28-4 (2S)-3-(benzyloxy)-2-methylpropanal 
• 63930-49-4 (R)-3-(benzyloxy)-2-methylpropan-1-ol 
• 73814-75-2 (2R,3S,4S)-5-benzyloxy-2,3-epoxy-4-methyl-1-pentanol 
• 155430-52-7 [(2R,3R)-3-((1R,2R,3S,4R,5R,6S,7S)-8-Benzyloxy-1,3,5,7-tetramethyl-2,4,6-tris-triethylsilanyloxy-octyl)-oxiranyl]-methanol 
• 155430-48-1 (E)-3-[(2S,3S)-3-((1S,2S,3R,4S,5S)-6-Benzyloxy-1,3,5-trimethyl-2,4-bis-triethylsilanyloxy-hexyl)-oxiranyl]-acrylic acid ethyl ester 
• 155430-46-9 (E)-3-[(2R,3R)-3-((1S,2S,3S)-4-Benzyloxy-1,3-dimethyl-2-triethylsilanyloxy-butyl)-oxiranyl]-acrylic acid ethyl ester 
• 155430-50-5 (E)-(4R,5R,6S,7S,8R,9S,10S)-11-Benzyloxy-5,7,9-trihydroxy-4,6,8,10-tetramethyl-undec-2-enoic acid ethyl ester 
• 155430-49-2 (E)-3-[(2S,3S)-3-((1R,2R,3R,4S,5S)-6-Benzyloxy-2,4-dihydroxy-1,3,5-trimethyl-hexyl)-oxiranyl]-acrylic acid ethyl ester 
• 618096-10-9 (E)-(4S,5R,6S)-7-Benzyloxy-4,6-dimethyl-5-triethylsilanyloxy-hept-2-enoic acid ethyl ester 
• 155613-08-4 (E)-(4S,5S,6S,7S,8S)-9-Benzyloxy-5,7-dihydroxy-4,6,8-trimethyl-non-2-enoic acid ethyl ester 
• 155430-47-0 (E)-3-[(2R,3R)-3-((1R,2S,3S)-4-Benzyloxy-2-hydroxy-1,3-dimethyl-butyl)-oxiranyl]-acrylic acid ethyl ester 
• 155488-74-7 (E)-(4S,5R,6S)-ethyl 7-benzyloxy-5-hydroxy-4,6-dimethyl-2-heptenoate 

Relevant academic research and scientific papers

Synthetic Studies on Polypropionate Antibiotics Based on the Stereospecific Methylation of γ,δ-Epoxy Acrylates by Trimethylaluminum. A Highly Stereoselective Construction of the Eight Contiguous Chiral Centers of Ansa-chains of Rifamycins

A highly stereoselective construction of the eight contiguous chiral centers of ansa-chains of rifamycins has been accomplished by the iterative use of the stereospecific methylation of γ,δ-epoxy acrylates by trimethylaluminum which was recently developed